CH3ReO3-catalyzed oxidation of cholesta-5,7-dien-3β-yl acetate with the urea-hydrogen peroxide adduct under various conditions. Synthesis of the natural epoxy sterol 9α,11α-epoxy-5α-cholest-7-en-3β,5,6β-triol

Steroids

Volumn 67, Issue 7, 2002, Pages 661-668

  Musumeci, Domenica ^a   Sica, Donato ^a  

^a UNIVERSITY OF NAPLES FEDERICO II   (Italy)

Author keywords

Catalysis; Cytotoxic sterol; Epoxides; Methyltrioxorhenium; Oxidation; Unsaturated diols

Indexed keywords

5,6 DIHYDROXY 5 ALPHA CHOLEST 7 EN 3BETA YL ACETATE; ACETIC ACID DERIVATIVE; EPOXIDE; ETHER; ETHER DERIVATIVE; HYDROGEN PEROXIDE; LIGAND; NATURAL PRODUCT; PYRIDINE DERIVATIVE; RHENIUM; SOLVENT; STEROL; UNCLASSIFIED DRUG; UREA;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; CYTOTOXICITY; OXIDATION; REACTION TIME; SPECTROSCOPY; STEROIDOGENESIS;

CATALYSIS; CHOLESTADIENES; CHOLESTEROL; HYDROGEN PEROXIDE; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; STEROLS; UREA;

EID: 0036239851     PISSN: 0039128X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0039-128X(02)00017-X     Document Type: Article

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