Modeling of iodine radiation chemistry in the presence of organic compounds

Radiation Physics and Chemistry

Volumn 64, Issue 3, 2002, Pages 203-213

  Taghipour, Fariborz ^a   Evans, Greg J ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

Iodine; Modeling; Organic iodide; Volatility

Indexed keywords

IODINE; ORGANIC COMPOUNDS; VAPORIZATION;

SEMI-MECHANISTIC REACTIONS;

RADIATION CHEMISTRY;

AROMATIC AMIDE; CARBONYL DERIVATIVE; HALIDE; IODINE; ORGANIC COMPOUND;

ARTICLE; CHEMICAL REACTION; KINETICS; MODEL; RADIOCHEMISTRY; SIMULATION; VOLATILIZATION;

EID: 0036229088     PISSN: 0969806X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0969-806X(01)00495-9     Document Type: Article

References (53)

1. Temperature dependence of the rate of reaction of OH with some aromatic compounds in aqueous solution. Evidence for the formation of a π-complex intermediate?
2. The radiolysis of aqueous solutions of methylene chloride
3. 2 in aqueous solution
4. Results from phase 2 of the radioiodine test facility experimental program
5. International Standard Problem (ISP) No. 41 computer code comparison exercise based on a Radioiodine Test Facility (RTF) experiment on iodine behaviour in containment under severe accident conditions
6. Chemistry and mass transfer of iodine in containment
7. The use of FACSIMILE program in the speciation of iodine in a PWR reactor containment following a loss of coolant accident
8. Future assessment of the chemical modeling of iodine in IMPAIR-3 code using ACE/RTF data
9. Volatile organic iodine formation by surface processes
10. Superoxide radical reactions in aqueous solutions of pyrogallol and n-propyl gallate: The involvement of phenoxyl radicals. A pulse radiolysis study
11. Modification of the INSPECT model
12. Measurement and modeling of iodine volatility above irradiated CsI solutions
13. 4-, Mn(II), phenoxide ion, and phenol
14. Advanced containment experiments: Evaluation of pre-test code calculations of iodine behavior in the radioiodine test facility
15. Advancements of radiation induced degradation of pollutants in drinking and waste water
16. Decomposition of biological resistant pollutants in water by irradiation
17. Radiolysis and pulse radiolysis of chlorinated phenols in aqueous solutions
18. Rate constants for reaction of hydroxyl radicals with several drinking water contaminants
19. Validation of the IODE code on analytical experiments
20. Relationship between the quantum yields of electron photoejection and fluorescence of aromatic carboxylate anions in aqueous solution
21. Rate constants for the reactions of free radicals with oxygen in solution
22. Kinetics of the reactions between alkyl radicals and molecular oxygen in aqueous solution
23. - and ·OH with 2-butanone and propanal
24. Rate constants and arrhenius parameter determination for the reaction of the hydrated electron with iodomethane, iodoethane, 1-iodopropane and 2-iodopropane in aqueous solution
25. Absolute rate constant measurements for the reaction of atomic hydrogen with acetone, 2-butanone, propionaldehyde, and butyraldehyde in aqueous solution
26. Rate constant and activation energy measurement for the reaction of atomic hydrogen with methanol, iodomethane, iodoethane, and 1-iodopropane in aqueous solution
27. Arrhenius parameter determination for the reaction of methyl radicals with iodine species in aqueous solution
28. Rate constants for oxidation reactions by radical cations from methyl iodide
29. An electron spin resonance study of the rate constants for reaction of hydrogen atoms with organic compounds in aqueous solution
30. Primary circuit iodine model addition to IMPAIR-3
31. 2· equilibria in aqueous solution. A pulse radiolysis study
32. Parametric studies of radiolytic oxidation of iodide solutions with and without paint: Comparison with code calculations
33. SMART: A simple model for activity removal and transport
34. Solvent and isotope effects on addition of atomic hydrogen to benzene in aqueous solution
35. The elucidation of peroxyl radical reactions in aqueous solution with the help of radiation-chemical methods
36. Radiolysis of water at elevated temperatures. III. Simulation of radiolytic products at 25°C and 250°C under the irradiation with γ-rays and fast neutrons
37. Radiolysis of water at elevated temperatures. III. Simulation of radiolytic products at 25°C and 250°C under the irradiation with γ-rays and fast neutrons
38. Radiolytic organic iodide formation under nuclear reactor accident conditions
39. Radioiodine volatilization in the presence of organic compounds
40. Iodine behaviour under conditions relating to nuclear reactor accidents
41. A generic overview of severe accident phenomena
42. Superoxide radical scavenging activity of phenolic compounds
43. The formation and volatility of organic iodides
44. Modeling of iodine chemistry: The LIRIC database
45. Modeling iodine behavior using LIRIC 3.0