Evaluation of the complexation behavior between humic acid and UO22+ with fluorescence spectroscopy and its mixture analysis

Radiochimica Acta

Volumn 90, Issue 37257, 2002, Pages 27-33

  Saito, Takumi ^a   Tanaka, Satoru ^a   Nagasaki, Shinya ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

Complexation; Fluorescence spectroscopy; Humic acid; SIMPLISMA; Uranyl ion

Indexed keywords

HUMIC ACID; URANIUM DIOXIDE;

ARTICLE; CHEMICAL COMPOSITION; CHEMICAL REACTION; COMPLEX FORMATION; FLUORESCENCE SPECTROSCOPY; MATHEMATICAL MODEL; REACTION ANALYSIS; THEORY;

EID: 0036162921     PISSN: 00338230     EISSN: None     Source Type: Journal    
DOI: 10.1524/ract.2002.90.1_2002.27     Document Type: Article

References (31)

1. Ziechmann, W.: Evoluation of Structural Models from Consideration of Physical and Chemical Properties. In: Humic Substances and their Role in the Environment. (Frimmel, F. H., Christian, R. F. Eds.) John Wiley & Sons, New York (1988).
2. Gaffney, J. S., Marley,N. A., Clark, S. B.: Humic and Fulvic Acids and Organic Colloidal Materials in the Environment. In: Humic and Fulvic Acids (ACS SYMPOSIUM SERIES 651). (Gaffney, J. S., Marley, N. A., Clark, S. B. Eds.) American Chemical Society, Washington, DC (1996).
3. Jones, M. N., Bryan, N. D.: Colloidal properties of humic substances. Adv. Colloidal Interface Sci. 78, 1 (1998).
4. Wittbrodt, P. R., Palmer, C. D.: Reduction of Cr(VI) in the presence of exces soil fulvic acid. Environ. Sci. Technol. 29, 255 (1995).
5. Lui, A., Gonzales, R. D.: Adsorption/desorption in a system of humic acid, heavy metals and clay minerals. J. Colloid Interface Sci. 218, 225 (1999).
6. nd Technical Progress. EC Project (Buckau, G. Ed.) Forschungszentrum Karlsruhe (1999).
7. Choppin, G. R.: The role of natural organics in radionuclide migration in natural aquifer systems. Radiochim. Acta 58/59, 113 (1992).
8. Murphy, R. J., Lenhart, J., Honeyman, B. D.: The sorption of thorium (IV) and uranium (VI) to hematite in the presence ofnatural organic matter. Colloidal Surf. 157, 47 (1999).
9. Benes, P., Kratzer, K., Vlckova, S., Sebestova, E.: Adsorption of uranium on clay and the effect of humica substances. Radiochim. Acta 82, 367 (1998).
10. Zeh. P., Kim, J. I., Marquardt, C. M., Artinger, R.: The reduction of Np(V) in groundwater rich in humic substances. Radiochim. Acta 87, 23 (1999).
11. Czerwinski, K. R., Buckau, G., Scherbaum, F., Kim, J. I.: Complexation of the uranyl ion with aquatic humic acid. Radiochim. Acta 65, 111 (1994).
12. Lubal, P., Fetsch, D., Siroky, D., Lubalova, M., Senkyr, J., Havel, J.: Potentiometric and spectroscopic study of uranyl complexation with humic acids. Talanta 51, 977 (2000).
13. Gamble, D. S.: Copper(II) titration of fulvic acid ligand sites with theoretical, ptentiometric, and spectrophotmetric analysis. Anal. Chim. 52, 1901 (1980).
14. Pompe, S., Brachmenn, A., Bubner, M., Geipel, G., Heise, K. H., Bernhard, G., Nitsche, H.: Determination and comparison of uranyl complexation constants with natural and model humic acids. Radiochim. Acta 82, 89 (1998).
15. Mobed, J. J., Hemmingsen, S. L., Autry, J. L., Mcgown, L. B.: Fluorecence characterization of IHSS humic substances: total luminescence spectra with absorption correction. Environ. Sci. Technol. 30, 3061 (1996).
16. Smith, D. S., Kramer, J. R.: Fluorescence analysis for multi-site aluminum binding to natural organic matter. Environ. Int. 25, 295 (1999).
17. Luster, J., Lloyd, T., Sposito, G.: Multi-wavelength molecular fluorescence spectrometry for quantitative characterization of Copper(II) complexation by dissolved organic matter. Environ. Sci. Technol. 30, 1565 (1996).
18. Miano, T. M., Sposito, G., Martin, J. P.: Fluorescence spectroscopy of humic substances. Soil Sci. Soc. Am. J. 52, 1016 (1988).
19. Esteves da Silva, J. C. G., Machado, A. A. S. C.: Procedure for classification of fulvic acids and similar substances based on the variation with pH of their synchronous spectra. Analyst 122, 1299 (1997).
20. Cabanlss, S. E.: Synchronous fluorescence spectra of metal-fulvic acid complexes. Environ. Sci. Technol. 26, 1133 (1992).
21. Esteves da Silva, J. C. G., Machado, A. A. S. C.: Evolving factor analysis of synchronous fluorescence spectra of humic substances in the prescence of Cu(II). Chemom. Intell. Lab. Syst. 27, 115 (1995).
22. Silva, C. S. P. C. O., Esteves da Silva, J. C. G., Machado, A. A. S. C.: Evolving factor analysis of synchronous fluorescence spectra of fulvic acids in the presence of aluminum. Appl. Spectrosc. 48, 363 (1994)
23. Windig, W., Guilment, J.: Interactive self-modeling mixture analysis. Anal. Chem. 63, 1425 (1991).
24. 2+ by self-modelling mixture analysis of synchronous molecular fluorescence spectra. Analyst 121, 1373 (1996).
25. Smith, D. S. Kramer, J. R.: Multisite metal binding to fulvic acid determined using multiresponse fluorescence. Anal. Chim. Acta 416, 211 (2000).
26. Ryan D. K., Weber, H.: Fluorescence quenching titration for determination of complexing capacities and stability constants of fulvic acid. Anal. Chem. 54, 986 (1982).
27. Kim, J. I., Buckau, G., Duschner, H., Pasrros,N.: Characterization of humic and fulvic acids from Gorleben groundwater. Fresenius J. Anal. Chem. 338, 245 (1990).
28. Lenhart, J. J., Cabaniss, S. E., MacCarthy, P., Honeyman, B. D.: Uranium(VI) complexation with citric, humic and fulvic acid. Radiochim. Acta 88, 345 (2000).
29. Grenthe, I., Fuger, J., Konings, R. J. M., Lemire, R. J., Müller, A. B., Trung, C. N., Wanner, H.: Chemical Thermodynamics of Uranium. North-Holland, Amsterdam (1992).
30. Goncalves, M. L. S., Mota, A. M.: Complexes of vanadyl and uranyl ions with the chelating groups of humic matter. Talanta 34, 839 (1987).
31. Machado, A. A. S. C., Esteves da Silva, J. C. G., Maria, J. A. C.: Multi-wavelength analysis of synchronous fluorescence spectra of the complexes between a soil fulvic acid and Cu(II). Anal. Chim. Acta 292, 121 (1994).