Thermodynamic model for the solubility of Cr(OH)3(am) in concentrated NaOH and NaOH-NaNO3 solutions

Journal of Solution Chemistry

Volumn 31, Issue 5, 2002, Pages 343-367

  Rai, Dhanpat ^a   Hess, Nancy J ^a   Rao, Linfeng ^b   Zhang, Zhicheng ^b   Felmy, Andrew R ^a   Moore, Dean A ^a   Clark, Sue B ^c   Lumetta, Gregg J ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^c WASHINGTON STATE UNIVERSITY   (United States)

Author keywords

Cr(OH)3(am); Cr(OH)4 ; Cr2O2(OH)42 ; Hydrolysis constants; Ion interaction parameters; Polynuclear species; Solubility; Thermodynamics

Indexed keywords

CHROMIUM; SODIUM HYDROXIDE; SODIUM NITRATE;

ARTICLE; CONCENTRATION RESPONSE; EQUILIBRIUM CONSTANT; MOLECULAR INTERACTION; OXIDATION; PREDICTION; REACTION ANALYSIS; ROENTGEN SPECTROSCOPY; ROOM TEMPERATURE; SLUDGE; SOLUBILITY; TEMPERATURE SENSITIVITY; THERMODYNAMICS;

EID: 0036085875     PISSN: 00959782     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1015887414411     Document Type: Article

References (40)

1. P. Hrma, J. Vienna, J. Crum, G. Piepel, and M. Mika, Mater. Res. Soc. Proc. 608, 671 (2000).
2. J. L. Swanson, Clean Option: An Alternative Strategy for Hanford Tank Waste Remediation. Volume 2: Detailed Description of First Example Flowsheet, PNL-8288, Vol 2 (Pacific Northwest National Laboratory, Richland, Washington, 1993).
3. G. J. Lumetta and B. M. Rapko, Separation Sci. Technol. 34, 1495 (1999).
4. B. M. Rapko, G. J. Lumetta, and M. J. Wagnor, Washing and Caustic Leaching of Hanford Tank Sludges: Results of FY 1995 Studies, PNL-10712 (Pacific Northwest National Laboratory, Richland, Washington, 1995).
5. G. J. Lumetta, B. M. Rapko, M. J. Wagner, J. Liu, and Y. L. Chen, Washing and Caustic Leaching of Hanford Tank Sludge: Results of FY 1996 Studies, PNNL-11278, Rev. 1 (Pacific Northwest National Laboratory, Richland, Washington, 1996).
6. G. J. Lumetta, I. E. Burgeson, M. J. Wagnor, J. Liu, and Y. L. Chen, Washing and Caustic Leaching of Hanford Tank Sludge: Results of FY 1997 Studies, PNNL-11636 (Pacific Northwest National Laboratory, Richland, Washington, 1997).
7. M. J. Kupfer, A. L. Boldt, K. M. Hodgson, L. W. Shelton, B. C. Simpson, R. A. Watrous, B. A. Higley, R. M. Orme, M. D. LeClair, G. L. Borsheim, R. T. Winward, N. G. Colton, S. L. Lambert, D. E. Place, and W. W. Schultz, Standard Inventories of Chemicals and Radionuclides in Hanford Site Tanks, HNF-SD-WM-TI-740, Rev 0B (Lockheed Martin Hanford Company, Richland, Washington, 1998).
8. D. L. Blanchard, S. D. Conradson, N. J. Hess, and P. K. Melethil, Sludge Component Speciation: Summary Final Report, TWRSPP-95-048 (Pacific Northwest National Laboratory, Richland, Washington, 1995).
9. J. D. Anderson, A History of the 200 Area Tank Farms, WHC-MR0132 (Westinghouse Hanford Company, Richland, Washington, 1990).
10. N. G. Colton, Status Report: Pretreatment Chemistry Evaluation FY1997 - Wash and Leach Factors for the Single-Shell Waste Inventory, PNNL-11646 (Pacific Northwest National Laboratory, Richland, Washington, 1997).
11. D. Rai and J. M. Zachara, Sci. Total Environ. 86, 15 (1989).
12. J. P. LaFemina, Tank Waste Treatment Science Task Quarterly Report for April-June 1995, PNL-10764 (Pacific Northwest National Laboratory, Richland, Washington 1995).
13. R. Fricke, and O. Windhausen, Z. Anorg. Allgem. Chem. 132, 273 (1924).
14. D. Rai, B. M. Sass, and D. A. Moore, Inorg. Chem. 26, 345 (1987).
15. S. E. Ziemniak, M. E. Jones, and K. E. S. Combs, J. Solution Chem. 27, 33 (1998).
16. von U. von Meyenburg, O. Sirok, and G. Schwarzenbach, Helv. Chim. Acta 56, 1099 (1973).
17. J. W. Ball, and D. K. Nordstrom, J. Chem. Eng. Data 43, 895 (1998).
18. K. B. Olsen, J. Wang, R. Setiadji, and J. Lu, Environ. Sci. Technol. 28, 2074 (1994).
19. R. C. Weast, Handbook of Chemistry and Physics (CRC Press, Boca Raton, 7L Ohio FL 1972-1973).
20. B. K. Teo, EXAFS: Basic Principles and Data Analyses, Inorganic Chemistry Concepts 9 (Springer-Verlag, New York, 1986).
21. A. N. Christensen, P. Hansen, and M. S. Lehmann, J. Solid State Chem. 21, 325 (1977).
22. A. N. Christensen, P. Hansen, and M. S. Lehmann, J. Solid State Chem. 19, 299 (1976).
23. K. S. Pitzer and G. Mayorga, J. Phys. Chem. 77, 2300 (1973).
24. K. S. Pitzer, Ion Interaction Approach: Theory and Data Correlation (CRC Press, Boca Raton, FL, 1991), Chap. 3.
25. A. R. Felmy and J. H. Weare, Geochim. Cosmochim. Acta 50, 2771 (1986).
26. A. R. Felmy, D. Rai, J. A. Schramke, and J. L. Ryan, Radiochim. Acta 48, 29 (1989).
27. S. M. Sterner, A. R. Felmy, J. R. Rustad, and K. S. Pitzer, Thermodynamic Analysis of Aqueous Solutions Using INSIGHT, PNWD-SA-4436 (Pacific Northwest National Laboratory, Richland, Washington, 1997).
28. D. Rai, A. R. Felmy, and R. W. Szelmeczka, J. Solution Chem. 20, 375 (1991).
29. D. Rai, A. R. Felmy, S. M. Sterner, D. A. Moore, and M. J. Mason, Radiochim. Acta 79, 239 (1997).
30. J. R. Smyth and D. L. Bish, Crystal Structures and Cation Sites of the Rock-Forming Minerals (Allen and Unwin, Boston, MA, 1988).
31. K. Bornholdt, J. M. Corker, J. Evans, and J. M. Rummey, Inorg. Chem. 30, 1 (1991).
32. S. M. Bradley, C. R. Lehr, and R. A. Kydd, J. Chem. Soc. Dalton Trans., p. 2415 (1993).
33. D. J. Wesolowski, Geochim. Cosmochim. Acta 56, 1065 (1992).
34. L. A. Laswick and R. A. Plane, J. Amer. Chem. Soc. 81, 3564 (1959).
35. R. W. Kolaczkowski and R. A. Plane, Inorg. Chem. 3, 322 (1964).
36. J. E. Finholt, M. E. Thompson, and R. E. Connick, Inorg. Chem. 20, 4151 (1981).
37. H. Stunzi, L. Spiccia, F. P. Rogzinger, and W. Marty, Inorg. Chem. 28, 66 (1989).
38. M. Thompson and R. E. Connick, Inorg. Chem. 20, 2279 (1981).
39. H. T. Hall and H. Eyring, J. Amer. Chem. Soc. 72, 782 (1950).
40. L. Rao, D. Rai, A. R. Felmy, R. W. Fulton, and C. F. Novak, Radiochim. Acta 75, 141 (1996).