Proton transfer from alkane radical cations to alkane molecules: Selectivity with respect to the site of proton donation and proton acceptance

Accounts of Chemical Research

Volumn 35, Issue 7, 2002, Pages 523-531

  Ceulemans, Jan ^a  

^a UNIVERSITY OF LEUVEN   (Belgium)

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE; PROTON;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BINDING; CHEMICAL STRUCTURE; ELECTRON SPIN RESONANCE; GAMMA IRRADIATION; GAS CHROMATOGRAPHY; MELTING POINT; PROTON TRANSPORT;

EID: 0036065372     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar0100430     Document Type: Article

References (24)

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2. 3F matrices at 77 K
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4. 3F matrices at 77 K
5. 3F matrices at 77 K
6. + of primary alkanes: ESR evidence
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8. 2- structure and reactions at low temperature
9. 8 n-alkane cations in halogenated matrices
10. The fate of alkane radical cations in liquid and solid hydrocarbons. Time-resolved fluorescence detected magnetic resonance
11. The crystal structure of lower paraffins. IV. Refinement of the crystal structures of pentane and octane
12. Linear alkane radical cations prepared in synthetic zeolites by irradiation at 4 K: ESR evidence for ion-molecule reaction to form 1-alkyl radicals
13. ESR, structure and reactions of specifically deuterium-labeled pentane cations in X-irradiated freon matrices
14. Structures and reactions of radical cations of linear alkanes: ESR evidence for selective deprotonation
15. +
16. Stabilization energy and ion size in carbocations in the gas phase
17. 3F/undecane
18. 3F/decane at 77 K
19. 18 crystals at 77 K
20. ESR and optical studies of solute n-alkane cations formed in γ-irradiated n-pentane and n-hexane matrices
21. 18 systems. Proton transfer as an alternative process to hole transfer in irradiated solid binary alkane systems
22. 13Cl crystals at 77 K
23. Proton acceptor site selectivity in the proton transfer from heptane radical cations to decane molecules in γ-irradiated heptane/decane/1-chloroheptane crystals at 77 K
24. Matrix effects on the photodissociation of alkane radical cations. Nature of the photodissociation of heptane radical cations in perfluorohexane and 1,1,2-trichlorotrifluoroethane matrices at cryogenic temperatures