First high-nuclearity thallium-palladium carbonyl phosphine cluster, [Tl2Pd12(CO)9 (PEt3)9]2+, and its initial mistaken identity as the unknown Au2Pd12 analogue: Structure-to-synthesis approach concerning its formation

Journal of the Chemical Society, Dalton Transactions

Volumn , Issue 22, 2002, Pages 4116-4127

  Ivanov, Sergei A ^a   Nichiporuk, Rita V ^a   Mednikov, Eugeny G ^a   Dahl, Lawrence F ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE COUPLED DEVICES; LOW TEMPERATURE OPERATIONS; STRUCTURE (COMPOSITION); SYNTHESIS (CHEMICAL); X RAY DIFFRACTION;

BONDING ENERGY;

THALLIUM COMPOUNDS;

EID: 0036027055     PISSN: 1470479X     EISSN: None     Source Type: Journal    
DOI: 10.1039/b204276m     Document Type: Article

References (119)

1. (a) J.-L. Malleron, J.-C. Fiaud and J. Y. Legros, Handbook of Palladium Catalyzed Organic Reactions, Academic Press, San Diego, CA, 1997;
2. (b) J.-L. Malleron, A. Juin, Database of Palladium Chemistry, Academic Press, San Diego, CA, 1997;
3. (c) W. M. H. Sachtler and A. Yu. Stakheev, Catal. Today, 1992, 12, 283 and references therein;
4. (d) Z. Zhang, A. P. Cavalcanti and W. M. H. Sachtler, Catal. Lett., 1992, 12, 157;
5. (e) Z. Zhang, L. Xu and W. M. H. Sachtler, J. Catal., 1991, 131, 502;
6. (f) L. Xu, G.-D. Lei, W. M. H. Sachtler, R. D. Cortright and J. A. Dumesic, J. Phys. Chem., 1993, 97, 11517 and references therein;
7. (g) J. H. Sinfelt, Bimetallic Catalysts: Discoveries, Concepts, and Applications, J. Wiley & Sons, New York, 1983, pp. 1-164; and references therein;
8. (h) J. H. Sinfelt, Acc. Chem. Res., 1987, 20, 134;
9. (i) P. Gallezot, "Metal clusters in zeolites," in Metal Clusters, ed. M. Moskovits, J. Wiley, New York, 1986, pp. 219-247;
10. (j) B. C. Gates, Catalytic Chemistry, J. Wiley, New York, 1992;
11. (k) P. R. Raithby, Platinum Met. Rev., 1998, 42, 146 and references therein;
12. (l) V. Ponec, Adv. Catal., 1983, 32, 149;
13. (m) P. Braunstein and J. Rose, in Comprehensive Organometallic Chemistry II, ed. E. W. Abel, F. G. A. Stone and G. Wilkinson, Elsevier, Tarrytown, NY, 1995, vol. 10, ed. R. D. Adams, ch. 7, 351;
14. (n) G. Süss-Fink and G. Meister, Adv. Organomet. Chem., 1993, 35, 41;
15. (o) Catalysis by Di- and Polynuclear Metal Cluster Complexes, ed. R. D. Adams and F. A. Cotton, Wiley-VCH, New York, 1998;
16. (p) Metal Clusters in Chemistry, ed. P. Braunstein, L. A. Oro and P. R. Raithby, Wiley-VCH, New York, 1999, vol. 2;
17. (q) Handbook of Heterogeneous Catalysis, ed. G. Ertl, H. Knözinger and J. Weitkamp, Wiley-VCH, New York, 1994;
18. (r) Applied Homogeneous Catalysis with Organometallic Compounds, ed. B. Cornils and W. A. Herrmann, Wiley-VCH, New York; vol. 1 (Applications), 1996; Applied Homogeneous Catalysis with Organometallic Compounds, ed. B. Cornils and W. A. Herrmann, Wiley-VCH, New York, vol. 2 (Developments), 1996;
19. (r) Applied Homogeneous Catalysis with Organometallic Compounds, ed. B. Cornils and W. A. Herrmann, Wiley-VCH, New York; vol. 1 (Applications), 1996; Applied Homogeneous Catalysis with Organometallic Compounds, ed. B. Cornils and W. A. Herrmann, Wiley-VCH, New York, vol. 2 (Developments), 1996;
20. (s) I. D. Salter, Adv. Organomet. Chem., 1989, 29, 249;
21. (t) I. D. Satler, in Comprehensive Organometallic Chemistry II, ed. E. W. Abel, F. G. A. Stone and G. Wilkinson, Elsevier, Tarrytown, NY, 1995, vol. 10, ed. R. D. Adams, ch. 5, p. 255;
22. (u) I. D. Salter, in Metal Clusters in Chemistry, ed. P. Braunstein, L. A. Oro and P. R. Raithby, Wiley-VCH, New York, 1999, vol. 1, p. 509;
23. (v) S.-M. Lee and W.-T. Wong, J. Cluster Sci., 1998, 9, 417;
24. (w) I. I. Moiseev and M. N. Vargaftik, New J. Chem., 1998, 22, 1217;
25. (x) T. A. Stromnova and I. I. Moiseev, Russ. Chem. Rev., 1998, 67, 485.
26. (a) L. H. Pignolet, M. A. Aubart, K. L. Craighead, R. A. T. Gould, D. A. Krogstad and J. S. Wiley, Coord. Chem. Rev., 1995, 143, 219 and references therein;
27. (b) D. A. Krogstad, W. V. Konze and L. H. Pignolet,Inorg. Chem., 1996, 35, 6763 and references therein;
28. (c) M. A. Aubart and L. H. Pignolet, J. Am. Chem. Soc., 1992, 114, 7901;
29. (d) T. G. M. M. Kappen, J. J. Bour, P. P. J. Schlebos, A. M. Roelofsen, J. G. M. van der Linden, J. J. Steggerda, M. A. Aubart, D. A. Krogstad, M. F. J. Schoondergang and L. H. Pignolet, Inorg. Chem., 1993, 32, 1074;
30. (e) M. A. Aubart, B. D. Chandler, R. A. T. Gould, D. A. Krogstad, M. F. T. Schoondergang and L. H. Pignolet, Inorg. Chem., 1994, 33, 3724;
31. (f) M. A. Aubart, J. F. D. Koch and L. H. Pignolet, Inorg. Chem., 1994, 33, 3852;
32. (g) L. I. Rubenstein and L. H. Pignolet, Inorg. Chem., 1996, 35, 6755;
33. (h) I. V. G. Graf, J. W. Bacon, M. B. Consugar, M. E. Curley, L. N. Ito and L. H. Pignolet, Inorg. Chem., 1996, 35, 689.
34. (a) M. Ichikawa, Advances in Catalysis, 1992, 38, 283 and references therein;
35. (b) L. Markó and A. Vizi Orosz, "Homogeneous catalysis by metal clusters," in Metal Clusters in Catalysis, ed. B. C. Gates and H. Knözinger, Elsevier, New York, 1986, pp. 89-120;
36. (c) L. Guczi, "Supported Bimetallic Catalysts Derived from Molecular Metal Clusters," in Metal Clusters in Catalysis, ed. B. C. Gates and H. Knözinger, Elsevier, New York, 1986, pp. 547-609;
37. (d) M. Ichikawa,Platinum Met. Rev., 2000, 44, 3 and references therein.
38. T. Kimura, A. Fukuoka, A. Fumagalli and M. Ichikawa, Catal. Lett., 1989, 2, 227.
39. (a) H. Bönnemann and R. M. Richards, Eur. J. Inorg. Chem., 2001, 2455;
40. (b) N. Toshima and T. Yonezawa, New J. Chem., 1998, 22, 1179.
41. N. T. Tran, D. R. Powell and L. F. Dahl, Angew. Chem., Int. Ed., 2000, 39, 4121.
42. R. Copley, C. M. Hill and D. M. P. Mingos, J. Cluster Sci., 1995, 6(1), 71.
43. M. Bochmann, I. Hawkins, M. B. Hursthouse and R. L. Short, Polyhedron, 1987, 6, 1987.
44. (a) A. D. Burrows and D. M. P. Mingos, Transition Met. Chem., 1993, 18, 129;
45. (b) A. D. Burrows and D. M. P. Mingos, Coord. Chem. Rev., 1996, 154, 19.
46. (a) E. G. Mednikov, N. K. Eremenko, S. P. Gubin, Yu. L. Slovokhotov and Yu. T. Struchkov, J. Organomet. Chem., 1982, 239, 401; E. G. Mednikov and N. K. Eremenko, Russ. Chem. Bull., 1983, 32, 2240 (Engl. Transl.);
47. (a) E. G. Mednikov, N. K. Eremenko, S. P. Gubin, Yu. L. Slovokhotov and Yu. T. Struchkov, J. Organomet. Chem., 1982, 239, 401; E. G. Mednikov and N. K. Eremenko, Russ. Chem. Bull., 1983, 32, 2240 (Engl. Transl.);
48. (b) D. M. P. Mingos and C. M. Hill, Croat. Chim. Acta, 1995, 68(4), 745.
49. (a) E. G. Mednikov, Yu. L. Slovokhotov and Yu. T. Struchkov, Metalloorg. Khim., 1991, 4, 123 (Organomet. Chem. USSR, 1991, 4, 65 (Engl. Transl.));
50. (b) E. G. Mednikov, N. K. Eremenko, Yu. L. Slovokhotov and Yu. T. Struchkov, J. Organomet. Chem., 1986, 301, C35; E. G. Mednikov, Organomet. Chem. USSR, 1991, 4, 433 (Engl. Transl.);
51. (b) E. G. Mednikov, N. K. Eremenko, Yu. L. Slovokhotov and Yu. T. Struchkov, J. Organomet. Chem., 1986, 301, C35; E. G. Mednikov, Organomet. Chem. USSR, 1991, 4, 433 (Engl. Transl.);
52. (c) E. G. Mednikov, N. K. Eremenko, Yu. L. Slovokhotov and Yu. T. Struchkov, Zh. Vses. Khim. O-va. Im. D. I. Mendeleeva, 1987, 32, 101 (Russ.); E. G. Mednikov, Russ. Chem. Bull., 1993, 42, 1242;
53. (c) E. G. Mednikov, N. K. Eremenko, Yu. L. Slovokhotov and Yu. T. Struchkov, Zh. Vses. Khim. O-va. Im. D. I. Mendeleeva, 1987, 32, 101 (Russ.); E. G. Mednikov, Russ. Chem. Bull., 1993, 42, 1242;
54. (d) E. G. Mednikov and N. I. Kanteeva, Russ. Chem. Bull., 1995, 44, 163;
55. (e) E. G. Mednikov, N. K. Eremenko, Yu. L. Slovokhotov and Yu. T. Struchkov, J. Chem. Soc., Chem. Commun., 1987, 218.
56. 1H} NMR spectra revealed these small resonances to be either fully resolved or coalesced into one broad resonance. Spectral resolution was usually achieved by slight solvent dilution of the sample, which may be indicative of molecular dynamic processes in solution
57. WinDNMR, Dynamic NMR Spectra for Windows, H. J. Reich, J. Chem. Educ.: Software, 1996, 3C2; 2.
58. WinDNMR, Dynamic NMR Spectra for Windows, H. J. Reich, J. Chem. Educ.: Software, 1996, 3C2; 2.
59. (a) N. K. Eremenko and S. P. Gubin, Pure Appl. Chem., 1990, 62, 1179;
60. (b) R. B. King, J. Cluster Sci., 1995, 6, 5.
61. (a) D. M. P. Mingos, J. Chem. Soc., Chem. Commun., 1983, 706;
62. (b) D. M. P. Mingos, J. Chem. Soc., Chem. Commun., 1985, 1352;
63. (c) D. M. P. Mingos, Acc. Chem. Res., 1984, 17, 311;
64. (d) D. M. P. Mingos, Polyhedron, 1984, 3, 1289;
65. (e) K. P. Hall and D. M. P. Mingos, Prog. Inorg. Chem., 1984, 32, 237;
66. (f) D. M. P. Mingos and R. L. Johnson, J. Organomet. Chem., 1985, 280, 419;
67. (g) D. M. P. Mingos and L. Zhenyang, J. Chem. Soc., Dalton Trans., 1988, 1657 and references therein;
68. (h) D. M. P. Mingos and A. P. May, in The Chemistry of Metal Cluster Complexes, ed. D. F. Shriver, H. D. Kaesz and R. D. Adams, VCH Publishers, New York, 1990, ch. 2, pp. 11-119;
69. (i) D. M. P. Mingos and D. J. Wales,Introduction to Cluster Chemistry, Prentice Hall, Old Tappan, NJ, 1990;
70. (j) D. M. P. Mingos and M. J. Watson, Adv. Inorg. Chem., 1992, 39, 327.
71. (a) N. T. Tran, M. Kawano and L. F. Dahl, J. Chem. Soc., Dalton Trans., 2001, 2731;
72. (b) see footnote 32 in ref. 17
73. (a) C. E. Briant, B. R. C. Theobald, J. W. White, L. K. Bell, D. M. P. Mingos and A. J. Welch, J. Chem. Soc., Chem. Commun., 1981, 201;
74. (b) M. Lapp and J. Strähle, Angew. Chem., Int. Ed. Engl., 1994, 33, 207;
75. (c) R. C. B. Copley and D. M. P. Mingos, J. Chem. Soc., Dalton Trans., 1992, 1755;
76. (d) B. K. Teo, H. Dang, H. Zhang, as quoted in H. Zhang and B. K. Teo, Inorg. Chim. Acta, 1997, 265, 213;
77. (e) B. K. Teo and H. Zhang, J. Organomet. Chem., 2000, 614, 66.
78. (a) N. Rösch, A. Görling, D. E. Ellis and H. Schmidbaur, Angew. Chem., Int. Ed. Engl., 1989, 28, 1357;
79. (b) P. Pyykkö, Chem. Rev., 1988, 88, 593;
80. (c) V. Bonacic-Koutecky, P. Fantucci and J. Koutecky, Chem. Rev., 1991, 91, 1035;
81. (d) K. S. Pitzer, Acc. Chem. Res., 1979, 12, 271;
82. (e) K. Balasubramanian, J. Phys. Chem., 1989, 93, 6585;
83. (f) P. Schwerdtfeger and P. D. W. Boyd, Inorg. Chem., 1992, 31, 327;
84. (g) P. Pyykkö and Y. Zhao,Angew. Chem., Int. Ed. Engl., 1991, 30, 604.
85. 20b from the Fenske-Hall MO method (ref. 21).
86. (a) A. J. Whoolery and L. F. Dahl, J. Am. Chem. Soc., 1991, 113, 6683;
87. (b) A. J. Woolery Johnson, B. Spencer and L. F. Dahl, Inorg. Chim. Acta, 1994, 227, 269.
88. M. B. Hall and R. F. Fenske, Inorg. Chem., 1972, 11, 768.
89. (a) A. D. Burrows, J. C. Machell and D. M. P. Mingos, J. Chem. Soc., Dalton Trans., 1992, 1939;
90. (b) V. J. Catalano, B. L. Bennett, R. L. Yson and B. C. Noll, J. Am. Chem. Soc., 2000, 122, 10056;
91. (c) A. L. Balch, B. J. Davis, E. Y. Fung and M. M. Olmstead, Inorg. Chim. Acta, 1993, 212, 149;
92. (d) O. J. Ezomo, D. M. P. Mingos and I. D. Williams, J. Chem. Soc., Chem. Commun., 1987, 924;
93. (e) L. Hao, J. J. Vittal and R. J. Puddephatt, Organometallics, 1996, 15, 3115; L. Hao, J. J. Vittal and R. J. Puddephatt, Inorg. Chem., 1996, 35, 269;
94. (e) L. Hao, J. J. Vittal and R. J. Puddephatt, Organometallics, 1996, 15, 3115; L. Hao, J. J. Vittal and R. J. Puddephatt, Inorg. Chem., 1996, 35, 269;
95. (f) G. J. Spivak, J. J. Vittal and R. J. Puddephatt, Inorg. Chem., 1998, 37, 5474.
96. E. G. Mednikov and N. K. Eremenko,Izv. Akad. Nauk SSSR, Ser. Khim., 1982, 2540 (2).
97. S. A. Ivanov, E. G. Mednikov, R. V. Nichiporuk, and L. F. Dahl, unpublished research, 2002.
98. E. G. Mednikov, S. A. Ivanov, and L. F. Dahl, unpublished research, 2002.
99. (a) R. D. Feltham, G. Elbaze, R. Ortega, C. Eck and J. Dubrawski, Inorg. Chem., 1985, 24, 1503;
100. (b) E. G. Mednikov, N. K. Eremenko, Yu. L. Slovokhotov, Yu. T. Struchkov and S. P. Gubin, Sov. J. Coord. Chem., 1987, 13(7), 979;
101. (c) N. K. Eremenko, E. G. Mednikov and S. P. Gubin, Sov. J. Coord. Chem., 1984, 10, 340.
102. S. A. Ivanov, M. A. Kozee, N. de Silva and L. F. Dahl, to be published.
103. b denotes the number of bonds used to calculate the error.
104. G. Sheldrick, SHELXTL (version 5.1), program library, Bruker Analytical X-Ray Systems, Madison, WI.
105. W. Kohn and L. J. Sham, Phys. Rev., 1965, 140, A1133.
106. (a) A. D. Becke, J. Chem. Phys., 1993, 98, 5648;
107. (b) K. Burke, J. P. Perdew, Y. Wang, in Electronic Density Functional Theory: Recent Progress and New Directions, ed. J. F. Dobson, G. Vignale and M. P. Das, Kluwer Academic/Plenum, New York, 1998;
108. (c) J. P. Perdew, J. A. Chevary, S. H. Vosko, K. A. Jackson, M. R. Pederson, D. J. Singh and C. Fiolhais, Phys. Rev. B, 1992, 46, 6671; J. P. Perdew, J. A. Chevary, S. H. Vosko, K. A. Jackson, M. R. Pederson, D. J. Singh and C. Fiolhais, Phys. Rev. B, 1993, 48, 4978;
109. (c) J. P. Perdew, J. A. Chevary, S. H. Vosko, K. A. Jackson, M. R. Pederson, D. J. Singh and C. Fiolhais, Phys. Rev. B, 1992, 46, 6671; J. P. Perdew, J. A. Chevary, S. H. Vosko, K. A. Jackson, M. R. Pederson, D. J. Singh and C. Fiolhais, Phys. Rev. B, 1993, 48, 4978;
110. (d) J. P. Perdew, K. Burke and Y. Wang, Phys. Rev. B, 1996, 54, 165333.
111. M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, V. G. Zakrzewski, J. A. Montgomery, Jr., R. E. Stratmann, J. C. Burant, S. Dapprich, J. M. Millam, A. D. Daniels, K. N. Kudin, M. C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi, B. Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G. A. Petersson, P. Y. Ayala, Q. Cui, K. Morokuma, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. Cioslowski, J. V. Ortiz, A. G. Baboul, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, C. Gonzalez, M. Challacombe, P. M. W. Gill, B. G. Johnson, W. Chen, M. W. Wong, J. L. Andres, M. Head-Gordon, E. S. Replogle and J. A. Pople, Gaussian 98 (Revision A.6), Gaussian, Inc., Pittsburgh, PA, 1998.
112. (a) P. J. Hay and W. R. Wadt, J. Chem. Phys., 1985, 82, 270-299;
113. (b) W. R. Wadt and P. J. Hay, J. Chem. Phys., 1985, 82, 284.
114. Ref. 225-248 in the manual for Gaussian 98 (ref. 32).
115. T. H. Dunning, Jr. and P. J. Hay, in Modern Theoretical Chemistry, ed. H. F. Schaefer, III, Plenum, New York, 1976, vol. 3, p. 1.
116. (a) E. D. Glendening, J. K. Badenhoop, A. E. Reed, J. E. Carpenter and F. Weinhold, NBO 4.0, Theoretical Chemistry Institute, University of Wisconsin, Madison, 1994;
117. (b) A. E. Reed, L. A. Curtiss and F. Weinhold, Chem. Rev., 1988, 88, 899;
118. (c) F. Weinhold, Natural bond orbital methods, in Encyclopedia of Computational Chemistry, ed. P. v. R. Schleyer, N. L. Allinger, T. Clark, J. Jasteiger and P. A. Kollman, Wiley, Chichester, UK, 1998, vol. 3, pp. 1792-1811;
119. (d) F. Weinhold and C. R. Landis, Chem. Educ.: Res. Pract. Eur., 2001, 2, 91.