Preparation, crystal structures and isomerization kinetics of cis- and trans-[Co(dtc)2(PHPh2)2]+: Thermodynamically and kinetically stable cobalt(III)-P bonds through interplay of σ-donicity, π-acidity, and steric bulkiness

Journal of the Chemical Society, Dalton Transactions

Volumn , Issue 18, 2002, Pages 3593-3602

  Iwatsuki, Satoshi ^a   Suzuki, Takayoshi ^a   Hasegawa, Atsushi ^a   Funahashi, Shigenobu ^a   Kashiwabara, Kazuo ^a   Takagi, Hideo D ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; ACIDITY; ADDITION REACTIONS; CHEMICAL BONDS; CRYSTAL STRUCTURE; DISSOCIATION; ISOMERIZATION; REACTION KINETICS; SYNTHESIS (CHEMICAL); THERMAL EFFECTS; THERMODYNAMIC PROPERTIES; X RAY CRYSTALLOGRAPHY;

COBALT DIPHENYLPHOSPHINE COMPLEXES; DONICITY; STERIC BULKINESS;

COBALT COMPOUNDS;

EID: 0036026136     PISSN: 1470479X     EISSN: None     Source Type: Journal    
DOI: 10.1039/b203792k     Document Type: Article

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