Synthesis and characterization of three new unsymmetrical porphyrins and their cobalt complexes

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

Volumn 32, Issue 5, 2002, Pages 843-851

  Lu, Xiaoquan ^a   Geng, Zaixin ^a   Wang, Yongsheng ^a   Lv, Baoqiang ^a   Kang, Jingwan ^a  

^a NORTHWEST NORMAL UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT COMPLEX; PORPHYRIN DERIVATIVE;

ARTICLE; INFRARED SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS; SYNTHESIS; ULTRAVIOLET SPECTROSCOPY;

EID: 0036022905     PISSN: 00945714     EISSN: None     Source Type: Journal    
DOI: 10.1081/SIM-120005606     Document Type: Article

References (22)

1. Lint, Z.M.; Feng, W.Z.; Leung, H.K. Sensitized Photoredox Reaction. Photoinduced Energy and Electron Transfer in Pyrene-porphyrin, Porphyrin-benzoquinone Binary Systems and the Pyrene-porphyrin-benzoquinone Ternary System. J. Chem. Commun. 1991, (4), 209-211.
2. Hill, G.l.; Brown, R.B. Sustained Epoxidation of Olefins by Oxygen Donors Catalyzed by Transition Metal Substituted Polyoxometalates, Oxidatively Resistant Inorganic Analogues of Metalloporphyrins. J. Am. Chem. Soc. 1986, 108 (3), 536-538.
3. Murray, R.I.; Silgar, S.G. Oxidative Cleavage of Phenyl-1,2-ethanediol by 4-Cyano-N, N-dimethylaniline N-Oxide and Chloro(5,10,15,20-tetraphenylporphinato)chromium(III), A Model for Cholesterol Side-chain Cleavage by Cytochrome P-450. J. Am. Chem. Soc. 1985, 107 (7), 2186-2187.
4. Hayashi, T.; Takimura, T.; Ohara, T.; Hitomi, Y.; Ogoshi, H. Photoinduced Electron Transfer from Zinc Porphyrin to a Linked Quinone in Myoglobin. J. Chem. Soc. Chem. Commun. 1995, 2503-2504.
5. Egger, N.G.; Motamedi.; Pow-Sang, M.; Orihuela, E.; Anderson, K.E. Accumulation of Porphyrins in Plasma and Tissues of Dogs after δ-Aminolevulinic Acid Administration: Implications for Photodynamic. Therapy. Pharmacology. 1996, 52 (6M.), 362-366.
6. Nakjima, S.; Sokaka, I.; Takemura, T. Mechanism of Accumulation Porphyrin Derivatives in Tumor Tissues and its Application to the Diagnosis and Treatment of Cancer. Drug. Delivery. Syst. 1996, 11 (2), 105-109.
7. 57 Tetraphenylporphinesulfonate in Cancer Patients. J. Nuclear. Medicine. 1964, 5, 462-470.
8. Kubat, P.; Mosinger, J. Photophysical Properties of Metal Complexes of meso-Tetrakis(4-sulfonatophenyl)porphyrin. J. Photochem. Photobiol. A. 1996, 96 (1-3), 93-96.
9. Zenkerich, E.; Sagun, E.; Knyukshtol, V.; Alexander, S.; Andrei, M.; Olga, E.; Kaymond, B.; Songa, S.P. Photophysical and Photochemical Properties of Potential Porphyrins and Chlorine Photosensitizer for PDT. J. Photochem. Photobiol. B. 1996, 33 (2), 171-175.
10. Kawamura-Konishi, Y.; Neya, S.; Norika, F.; Horuo, S. Spatial Orientation of Porphyrin at the Binding Site of Catalytic Antibody. Biochem. Biophys. Res. Commun. 1996, 225 (2), 537-542.
11. Karaman, R.; Blaskó, A.; Bruice, T. C. Symmetrical and Unsymmetrical Quadruply Aza-Bridged Closely Interspaced Cofacial Bis(5,10,15,20-tetraphenylporphyrin)s. 2. Synthesis, Characterization, and Conformational Effects of Solvents. J. Am. Chem. Soc. 1992, 114, 4889-4898.
12. Meot-Ner, M.; Adler, A.D. Substituent Effects in Noncoplanar π System. Ms-Porphins. J. Am. Chem. Soc. 1975, 97, 5107-5112.
13. Walker, F.A.; Beroiz, D.; Kadish, K.M. Electronic Effects in Transition Metal Porphyrins. 2. The Sensitivity of Redox and Ligand Addition Reaction in para-Substituted Teraphenylporphyrin Complexes of Cobalt(II). J. Am. Chem. Soc. 1976, 98, 3484-3489.
14. 2 Reduction on Water-soluble Phthalocyaines Adsorbed on Graphite Electrode. J. Electrochem. Soc. 1980, 127, 1506-1517.
15. Sawyer, T.; Seo, E. One-Electron Mechanism for the Electrochemical Reduction of Molecular Oxygen. Inorg. Chem. 1977, 16, 499-501.
16. Wilshire, J.; Sawyer, D.T. Redox Chemistry of Dioxygen Species. Acc. Chem. Res. 1979, 12, 105-111.
17. Geiger, T.; Anson, F.C. Homogeneous Catalysis of the Electrochemical Reduction of Dioxygen by a Macrocyclic Cobalt Complex. J. Am. Chem. Soc. 1981, 103, 7489-7495.
18. 12 by the Miocroaerophilic Organism, Propionibacterium Shermanii. J. Chem. Soc. Perkin Trans. I. 1999, 8, 537-541.
19. 12; Academic Press: New York, 1972.
20. Lu, X.Q.; Geng, Z.X.; Kang, J.W; Wang, Z.H.; Gao, J.Z. Synthesis and Characterization of Three New Unsymmetrical Porphyrins. Synth. Commun. 2000, 30 (12), 2213-2221.
21. Geng, Z.X. Synthesis, Properties, and Applications of the New porphyrins and metalloporphyrins in Electroanalytical Chemistry. Thesis of Master Degree. 2000, 52-53.
22. Yu, F.; Dong, B.W.; Hui, C.A. New Synthesis of meso-Tera[4-(carboxymethylenoxy)phenyl]porphyrin. Synth. Commun. 1998, 28 (12), 2843-2849.