Facile synthesis of 17-formyl steroids via palladium-catalyzed homogeneous carbonylation reaction

Steroids

Volumn 67, Issue 9, 2002, Pages 777-781

  Petz, Andrea ^a   Horváth, Judit ^b   Tuba, Z ^b   Pinter Z ^c   Kollar L ^a,c  

^a UNIVERSITY OF PÉCS   (Hungary)

^b GEDEON RICHTER LTD   (Hungary)

^c INSTITUTE OF EXPERIMENTAL MEDICINE   (Hungary)

Author keywords

17 Formyl steroids; 17 Iodo 16 enes; Carbonylation; Palladium catalysts; Steroids; Tributyltin hydride

Indexed keywords

PALLADIUM; STEROID; 17 IODO 3 METHOXYESTRA 1,3,5(10),16 TETRAENE; 17 IODO 4 AZA 4 METHYLANDROST 16 EN 3 ONE; 17 IODO 4 AZAANDROST 16 EN 3 ONE; 17 IODO 6BETA HYDROXY 3ALPHA,5ALPHA CYCLOANDROST 16 ENE; 17 IODOANDROST 16 ENE; ALKENE DERIVATIVE; BUTYLTIN DERIVATIVE; HYDROGEN; TRIBUTYLTIN HYDRIDE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; STRUCTURE ACTIVITY RELATION; SYNTHESIS; CARBONYLATION; CATALYST; CHEMICAL REACTION; DRUG SYNTHESIS; FORMYLATION; ISOMERISM;

CATALYSIS; MOLECULAR STRUCTURE; PALLADIUM; STEROIDS; STRUCTURE-ACTIVITY RELATIONSHIP; SUPPORT, NON-U.S. GOV'T;

EID: 0035996628     PISSN: 0039128X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0039-128X(02)00035-1     Document Type: Article

References (13)

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3. Palladium-catalysed synthesis of β,γ-unsaturated aldehydes
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5. Palladium-catalyzed formylation of organic halides with carbon monoxide and tin hydride
6. Synthesis, X-ray structure and molecular mechanics studies of the boar taint steroid (5α-androst-16-ene)
7. A new reaction of hydrazones
8. An improved preparation of vinyl iodides
9. NMR investigation of Pd(II)-Pd(0) reduction in the presence of mono and ditertiary phosphines
10. Stability indicating HPTLC method for the estimation of estradiol