A modified free-volume model: Correlation of ion-conduction in strongly associating polymeric materials

Journal of Membrane Science

Volumn 191, Issue 1-2, 2001, Pages 13-30

  Ramesh, Narayan ^a   Duda, J L ^a  

^a The Pennsylvania State University   (United States)

Author keywords

Free volume theory; Ion conduction; Ion hopping; Jumping unit; WLF equation

Indexed keywords

DIFFUSION; IONOMERS; POSITIVE IONS; VISCOSITY;

IONIC POLYMERS;

POLYMERS;

ION; POLYMER;

DIFFUSION; MEMBRANE; POLYMER;

ARTICLE; DIFFUSION; ION CONDUCTANCE; ION TRANSPORT; MOLECULAR WEIGHT; PRIORITY JOURNAL; TEMPERATURE; VISCOSITY;

EID: 0035975721     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0376-7388(01)00439-2     Document Type: Article

References (48)

1. Ion-containing polymers: Physical properties and structure
2. 6) electrolytes
3. Synthesis, NMR characterization, and electrical properties of siloxane-based polymer electrolytes
4. Synthesis and characterization of ionomeric poly(vinyl butyral)
5. 4 amorphous blends
6. Study on the electrical conduction mechanism of polypyrrole films
7. The mechanism of lithium ion transport in polyacrylonitrile-based polymer electrolytes
8. Mechanisms of ionic conductivity for zwitterionic polymers
9. Correlation between chain segment and ion mobility in an epoxy resin system: A free-volume analysis
10. The viscosity and ion conductivity of polydimethylsiloxane systems: 1. Chain length and ion size effects
11. The viscosity and ion conductivity of polydimethylsiloxane systems: 2. Ion concentration effects
12. Dynamics of lightly sulfonated polystyrene ionomers
13. Polyelectrolyte conductivity
14. Ionic conductivity of polymer electrolytes based on phosphate and polyether copolymers
15. Bulk properties of ionomers
16. Structure and properties of ionomers
17. Structure and applications of ion-containing polymers
18. Bulk properties of ionomers
19. A new multiplet-cluster model for the morphology of random ionomers
20. Crystallization and ionic associations in semicrystalline ionomers
21. Clustering on ions in organic polymers: A theoretical approach
22. Size and stabilities of multiplets and clusters in carboxylated and sulfonated styrene ionomers
23. Direct observation of ionic aggregates in sulfonated polystyrene ionomers
24. Low-shear melt rheology of partially neutralized ethylene-methacrylic acid ionomers
25. Structure and properties of hydrocarbon ionomer membranes. 1. Poly(methyl methacrylate-co-methacrylic acid)
26. The solid-state properties of ionomers, a comparison of ethylene and styrene based materials
27. Ion clustering and viscoelastic relaxation in styrene-based ionomers. II. Effect of ion concentration
28. Secondary relaxation behavior in ion-containing polymers
29. Ion clustering and viscoelastic relaxation in styrene-based ionomers. IV. X-ray and dynamic mechanical studies
30. Ion clustering and viscoelastic relaxation in styrene-based ionomers. III. Effect of counterions, carboxylic groups and plasticizers
31. Viscoelastic behavior of styrene/n-butyl-methacrylate/potassium methacrylate polymers
32. Diffusion in polymer-solvent systems. I. Re-examination of the free-volume theory
33. Diffusion in polymer-solvent Systems. II. A predictive theory for the dependence of diffusion coefficients on temperature, concentration and molecular weight
34. Diffusion in polymer-diluent systems
35. Predicting polymer-solvent diffusion coefficients using free-volume theory
36. Molecular diffusion in polymer solutions
37. Solvent self-diffusion in rubbery polymer-solvent systems
38. Effect of solvent size on solvent self-diffusion in polymer-solvent systems
39. Predictive methods for self-diffusion and mutual diffusion coefficients in polymer-solvent systems
40. Solvent self-diffusion in crosslinked polymers
41. Molecular weight dependence of the viscoelastic properties of polystyrene-based ionomers
42. Ionic conductivity of polymer electrolytes and future applications
43. Ion-hopping kinetics in three-arm star polyisobutylene-based model ionomers
44. Ionic aggregates in partially Zn-neutralized poly(ethylene-ran-methacrylic acid) ionomers: Shape, size and size distribution
45. Molecular volumes at absolute zero. II. Zero volumes and chemical composition