Synthesis and structure of new osmium-PCP complexes. Osmium-mediated C-C bond activation

Organometallics

Volumn 20, Issue 9, 2001, Pages 1719-1724

  Gauvin, Régis M ^a   Rozenberg, Haim ^a   Shimon, Linda J W ^a   Milstein, David ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CARBON MONOXIDE; CHEMICAL ACTIVATION; CHEMICAL BONDS; MOLECULAR STRUCTURE; OSMIUM COMPOUNDS; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION ANALYSIS;

DIPHOSPHINE; OSMIUM MEDIATED BOND ACTIVATION;

ORGANOMETALLICS;

EID: 0035972363     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000878z     Document Type: Article

References (32)

1. Moulton, C J.; Shaw, B. L. J. Chem. Soc., Dalton Trans. 1976, 1020.
2. Some examples: (a) Vigalok, A.; Shimon, L. J. W.; Milstein, D. J. Am. Chem. Soc. 1998, 120, 477.
3. (b) Vigalok, A.; Rybtchinski, B.; Shimon, L. J. W.; Ben-David Y.; Milstein, D. Organometallics 1999, 18, 895.
4. (c) Rybtchinski, B.; Ben-David, Y.; Milstein, D. Organometallics, 1997, 16, 3786.
5. (d) van der Boom, M. E.; Ben-David, Y.; Milstein, D. J. Am. Chem. Soc. 1999, 121, 6652.
6. (e) Ashkenazi, N.; Vigalok, A.; Parthiban, S.; Ben-David, Y.; Shimon, L. J. W.; Martin, J. M. L.; Milstein, D. J. Am. Chem. Soc. 2000, 122, 8797.
7. (a) Ohff, M.; Ohff, A.; van der Boom, M. E.; Milstein, D. J. Am. Chem. Soc. 1997, 119, 11687.
8. (b) Jensen, C. M. Chem. Commun. 1999, 2443.
9. (c) Morales-Morales, D.; Redon, R.; Yung, C.; Jensen, C. M. Chem. Commun. 2000, 1620:
10. (d) Dani, P.; Karlen, T.; Gossage, R. A.; Gladiali, S.; Van Koten, G. Angew. Chem., Int. Ed. 2000, 39, 743.
11. (a) Karlen, T.; Dani, P.; Grove, D. D.; Steenwinkel, P.; van Koten, G. Organometallics 1996, 15, 5687.
12. (b) Jia, G.; Lee, H. M.; Xia, H. P.; Williams, I. D. Organometallics 1996, 15, 5453.
13. (c) Dani, P.; Karlen, T.; Gossage, R. A.; Smeets, W. J. J.; Spek, A. L.; van Koten, G. J. Am. Chem. Soc. 1997, 119, 11317.
14. (d) Steenwinkel, P; Kolmschot, S.; Gossage, R. A.; Dani, P.; Veldman, N.; Spek, A. L.; van Koten, G. Eur. J. Inorg. Chem. 1998, 477.
15. (e) van der Boom, M. E.; Kraatz, H.-B.; Hassner, L.; Ben-David, Y.; Milstein, D. Organometallics 1999, 18, 3873.
16. (a) Wen, T. B.; Cheung, Y. K.; Yao, J.; Wong, W.-T.; Zhou, Z. Y.; Jia, G. Organometallics 2000, 19, 3803.
17. 3 ligands, Hoskin, S. V.; Rickard, C. E. F.; Roper, W. R. J. Chem. Soc., Chem. Commun. 1984, 1000.
18. (a) For a review on C-C bond activation with a particular emphasis on PCP systems, Rybtchinski, B.; Milstein, D. Angew. Chem., Int. Ed. 1999, 38, 870.
19. (b) C-O activation: van der Boom, M. E.; Liou, S.-Y.; Ben-David, Y.; Shimon, L. J. W.; Milstein, D. J. Am. Chem. Soc. 1998, 120, 6531.
20. van der Boom, M. E.; Liou, S.-Y.; Ben-David, Y.; Vigalok, A.; Milstein, D. Angew. Chem., Int. Ed. 1997, 36, 625.
21. (a) Hoffmann, P. R.; Caulton, K. G. J. Am. Chem. Soc. 1975, 97, 4221.
22. (b) Elliott, G. P.; McAley, N. M.; Roper, W. R. Inorg. Synth. 1989, 26, 184.
23. Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789.
24. Stolzenberg, A. M.; Muetterties, E. L. Organometallics 1985, 4, 1739.
25. Zassinovicth, G.; Mestroni, G.; Gladiali, S. Chem. Rev. 1992, 95, 1051.
26. Baker, L.-J.; Clark, G. R.; Rickard, C. E. F.; Roper, W. R.; Woodgate, S. D.; Wright, L. J. J. Organomet. Chem. 1998, 551, 247.
27. C-C cleavage by β-alkyl elimination in a Os complex has been postulated: (a) Edwards, A J.; Esteruelas, M. A.; Lahoz, F. J.; Lopez, A. M.; Onate, E.; Oro, L. A.; Tolosa, J. I. Organometallics 1997, 16, 1316.
28. For C-C activation by Os clusters, (b) Chi, Y.; Chung, C.; Chou, Y. C.; Su, P. C.; Chiang, S. J.; Peng, S. M.; Lee, G. H. Organometallics 1997, 16, 1702.
29. (c) Adams, R. D.; Qu, X. S. Organometallics 1995, 14, 4172.
30. (d) Park, T. J.; Woo, B. W.; Chung, J. H.; Shim, S. C.; Lee, J. H.; Lim, S. S.; Suh, I. H. Organometallics 1994, 13, 3384.
31. (e) Deeming, A. J.; Felix, M. S. B.; Nuel, D. Inorg. Chim. Acta 1993, 213, 3.
32. Fernando, G.; Caulton, K. G. Inorg. Chem. 1999, 38, 4168.