Synthesis, structural, and theoretical analysis of Ru4(CO)12(μ-PF2)(μ4-P): Is the μ4-P atom a three-electron or a five-electron donor?

Organometallics

Volumn 20, Issue 22, 2001, Pages 4469-4475

  Kahlal, Samia ^a   Wang, Weibin ^b   Scoles, Ludmila ^b   Udachin, Konstantin A ^b   Saillard, Jean Yves ^a   Carty, Arthur J ^b  

^a UNIVERSITÉ DE RENNES 1   (France)

^b NATIONAL RESEARCH COUNCIL CANADA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMIC SIZE; PYRAMIDALIZATION; X RAY MOLECULAR STRUCTURE;

CHEMICAL BONDS; ELECTRON TRANSITIONS; MOLECULAR STRUCTURE; PINCH EFFECT; PROBABILITY DENSITY FUNCTION; RUTHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL); TRANSITION METALS;

ORGANOMETALLICS;

EID: 0035969287     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010352u     Document Type: Article

References (42)

1. (a) Wade, K. In Transition Metal Clusters; Johnson, B. F. G., Ed.; Wiley: New York, 1980; p 193.
2. (b) Mingos, D. M. P.; Wales, D. J. Introduction to Cluster Chemistry; Prentice-Hall: Englewood Cliffs, NJ, 1990.
3. Adams, R. D.; Horvàth, I. T.; Segmüller, B. E.; Yang, L.-W. Organometallics 1983, 2, 1301.
4. Halet, J.-F. In Topics in Physical Organometallic Chemistry; Gielen, M. F., Ed.; Freund: London, 1992; Vol. 4, p 221.
5. Churchill, M. R.; Wormold, J.; Knight, J.; Mays, M. J. J. Am. Chem. Soc. 1971, 93, 3073.
6. Braye, E. H.; Dahl, L. F.; Hübel, W.; Wampler, D. L. J. Am. Chem. Soc. 1962, 84, 4633.
7. (a) Holt, E. M.; Whitmire, K. H.; Shriver, D. F. J. Organomet. Chem. 1981, 213, 125.
8. (b) Boeheme, R. F.; Coppens, P. Acta Crystallogr. 1981, B37, 1914.
9. (c) Davies, J. H.; Beno, M. A.; Williams, J. A.; Zimmie, J.; Tachikawa, M.; Muetterties, E. L. Proc. Natl. Acad. Sci. U.S.A. 1981, 78, 668.
10. (a) Muettertries, E. L. Chem. Rev. 1979, 79, 91.
11. (b) Muetterties, E. L. Prog. Inorg. Chem. 1981, 28, 203.
12. (c) Wijeyesekara, S. D.; Hoffmann, R.; Wilker, C. N. Organometallics 1984, 3, 962.
13. Halet, J.-F.; Saillard, J.-Y.; Lissillour, R.; McGlinchey, M. J.; Jaouen, G. Organometallics 1986, 5, 139.
14. (a) Kahlal, S.; Udachin, K. A.; Scoles, L.; Carty, A. J.; Saillard, J.-Y. Organometallics 2000, 19, 2251.
15. (b) Wang, W.; Corrigan, J. F.; Enright, G. D.; Taylor, N. J.; Carty, A. J. Organometallics 1998, 17, 427.
16. (c) Wang, W.; Carty, A. J. New J. Chem. 1997, 21, 773.
17. (d) Yamamoto, J. H.; Udachin, K. A.; Enright, G. D.; Carty, A. J. Chem. Commun. 1998, 2259.
18. (a) International Tables for X-ray Crystallography; Kynoch: Birmingham, U.K., 1975; Vol. IV, Table 2.2B, pp 99-101.
19. (b) International Tables for X-ray Crystallography; Kynoch: Birmingham, U.K., 1975; Vol. IV, Table 2.3.1, pp 149-150.
20. (a) Baerends, E. J.; Ellis, D. E.; Ros, P. Chem. Phys. 1975, 8, 41.
21. (b) Baerends, E. J.; Ros, P. Int. J. Quantum Chem. 1978, S12, 169.
22. (c) Boerrigter, P. M.; te Velde, G.; Baerends, E. Int. J. Quantum Chem. 1988, 33, 87.
23. (d) te Velde, G.; Baerends, E. J. J. Comput. Phys. 1992, 99, 84.
24. Amsterdam Density Functional (ADF) program, version 2.3; Vrije Universiteit, Amsterdam, The Netherlands, 1997.
25. Vosko, S. D.; Wilk, L.; Nusair, M. Can. J. Chem. 1990, 58, 1200.
26. Blenkiron, P.; Enright, G. D.; Low, P. J.; Corrigan, J. F.; Taylor, N. J.; Chiy, Y. Saillard, J.-Y.; Carty, A. J. Organometallics 1998, 17, 2447-2458.
27. All the bonding and nonbinding peripheral electrons which lie in the environment of the metal atoms have to be added to the skeletal electron number in order to reach the MVE count.
28. (a) Fjare, D. J.; Gladfelter, W. L. J. Am. Chem. Soc. 1981, 103, 1572.
29. (b) Harris, S.; Blohm, M. L.; Gladfeller, W. L. Inorg. Chem. 1989, 28, 2290.
30. (c) Collins, M. A.; Johnson, B. F. G.; Lewis, J.; Mace, J.; Morris, J.; McPartlin, N.; Nelson, W. J. H.; Puga, J.; Raithby, P. R. J. Chem. Soc., Chem. Commun. 1983, 689.
31. (a) Tachikawa, M.; Stein, J.; Muetterties, E. L.; Teller, R. G.; Beno, M. A.; Gebert, E.; Williams, J. M. J. Am. Chem. Soc. 1980, 102, 6648.
32. (b) Braga, D.; Johnson, B. F. G.; Lewis, J.; Mace, J. M.; McPartlin, M.; Puga, J.; Nelson, W. J. H.; Raithby, P. R.; Whitmire, K. H. J. Chem. Soc., Chem. Commun. 1982, 1081.
33. (c) Blohm, M. L.; Fjare, D. E.; Gladfelter, W. L. J. Am. Chem. Soc. 1986, 108, 2301.
34. (d) Fjare, D. E.; Gladfelter, W. L. J. Am. Chem. Soc. 1984, 106, 4799.
35. (a) Bradley, J. S.; Ansell, G. B.; Leonowicz, M. E.; Hill, E. W. J. Am. Chem. Soc. 1981, 103, 4968.
36. (b) Hriljac, J. A.; Swepston, P. N.; Shriver, D. F. Organometallics 1985, 4, 158.
37. (c) Chi, Y.; Chuang, S.-H.; Chen, B.-F.; Peng, S.-M.; Lee, G.-H. J. Chem. Soc., Dalton Trans. 1990, 3033.
38. Attard, J. P.; Johnson, B. F. G.; Lewis, J.; Mace, J. M.; Raithby, P. R. J. Chem. Soc., Chem. Commun. 1985, 1526.
39. Beringhelli, T.; Ciani, G.; D'Alfonso, G.; Sironi, A.; Freni, M. J. Chem. Soc., Chem. Commun. 1985, 978.
40. 2- is likely to be unstable.
41. (a) Halet, J. F.; Hoffmann, R.; Saillard, J.-Y. Inorg. Chem. 1985, 25, 1695.
42. (b) Halet, J.-F.; Saillard, J.-Y. New J. Chem. 1987, 11, 315.