Simultaneous determination of structural and kinetic parameters characterizing the interconversion of highly dispersed species: The interaction of NO with RhI(CO)2/γ-Al2O3

Journal of Physical Chemistry A

Volumn 105, Issue 25, 2001, Pages 5965-5970

  Newton, Mark A ^a   Burnaby, Daryl G ^a   Dent, Andrew J ^c   Diaz Moreno, Sofia ^b   Evans, John ^a   Fiddy, Steven G ^a   Neisius, Thomas ^b   Pascarelli, Sakura ^b   Turin, Sandra ^a  

^a UNIVERSITY OF SOUTHAMPTON   (United Kingdom)

^b EUROPEAN SYNCHROTRON RADIATION FACILITY   (France)

^c CLRC Daresbury Laboratories Daresbury   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

FLOW MICROREACTORS;

CHEMICAL REACTORS; MASS SPECTROMETRY; REACTION KINETICS; RHODIUM COMPOUNDS;

MOLECULAR STRUCTURE;

EID: 0035963810     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp011621x     Document Type: Article

References (30)

1. See, for instance: (a) Frahm, R. Nucl. Instrum. Methods A 1988, 270, 588.
2. (b) Dobson, B. R ; Hasnain, S. S.; Neu, M.; Ramsdale, C. A.; Murphy, L. M. Jpn. J. Appl. Phys. 1993, 32, 192.
3. Couves, J. W.; Thomas, J. M.; Catlow, R. A. J. Phys. Chem. 1990, 94, 6517.
4. Couves, J. W.; Thomas, J. M.; Waller, D.; Jones, R. H.; Dent, A. J.; Derbyshire, G. E.; Greaves, G. N. Nature 1991, 354, 465.
5. Sankar, G.; Wright, P. A.; Natarajan, S.; Thomas, J. M.; Greaves, G. N ; Dent, A. J.; Dobson, B. R.; Ramsdale, C. A ; Jones, R. H. J. Phys. Chem. 1993, 97, 9550.
6. Clausen, B. S.; Grabaek, L.; Steffensen, G.; Hansen, P. L.; Topsoe, H. Catal. Lett. 1998, 20, 23.
7. Cimini, F.; Prins, R. J. Phys. Chem. B 1997, 101, 5277.
8. Cattaneo, R.; Weber, T.; Shido, T.; Prins, R. J. Catal. 2000, 191, 25.
9. Als Nielsen, J.; Grubel, G.; Clausen, B. S. Nucl. Instrum. Methods B 1995, 97, 522.
10. Hagelstein, M ; Ferraro, C.; Hatje, U.; Ressler, T.; Metz, U. J. Synchrotron Radiat. 1995, 2, 174.
11. (a) Ressler, T.; Hagelstein, M.; Hatje, U.; Metz, W. J. Phys. Chem. B 1997, 101, 6680.
12. (b) Ressler, T.; Timpe, O.; Neisius, T.; Find, J.; Mestl, G.; Dieterle, M.; Schlogl, R. J. Catal. 2000, 191, 75.
13. See, for instance: Van Der Venne, J. L.; Rindt, J. P. M.; Coenen, G. J. M. M. J. Colloid Interface Sci. 1990, 74, 287.
14. Conner, W. C.; Weist, E. L.; Ito, T.; Fraissard, J. J. Phys. Chem. 1989, 93, 4138.
15. (a) Fiddy, S. G.; Newton, M. A.; Dent, A. J.; Salvini, G.; Corker, J. M.; Turin, S.; Campbell, T.; Evans, J. Chem. Commun. 1999, 851.
16. (b) Fiddy, S. G.; Newton, M. A.; Campbell, T.; Corker, J. M.; Dent, A. J.; Harvey, I.; Salvini, G.; Turin, S ; Evans, J. Chem. Commun. 2001, 445.
17. Newton, M. A ; Burnaby, D. G.; Dent, A. J.; Diaz-Moreno, S.; Evans, J.; Fiddy, S. G.; Neisius, T.; Turin, S. Manuscript in preparation.
18. (a) Binsted, N. PAXAS, Programme for the Analysis of X-ray Absorption Apectra; University of Southampton: Southampton, U.K., 1988.
19. (b) Binsted, N. EXCURV98, CCLRC Daresbury Laboratory Computer Programme; University of Southampton: Southampton, U.K., 1998.
20. (a) Galas, J. M. R.; Hursthouse, M. B.; Moore, D. S.; Robinson, S. D. Inorg. Chim. Acta 1983, 77, L135.
21. (b) Goldberg, S. Z.;, Kubiak, C.; Meyer, C. D.; Eisenberg, R. Inorg. Chem. 1975, 14, 1650.
22. See, for instance: Eisenberg, R.; Meyer, C. D. Acc. Chem. Res. 1975, 8, 26.
23. Kaduk, J. A.; Ibers, J. A. Inorg. Chem. 1975, 14, 3071.
24. Laidler, K. J. Chemical Kinetics, 10th ed.; McGraw-Hill: New York, 1984.
25. See, for instance: Satterfield, C. Heterogeneous Catalysis in Practice; McGraw Hill Chem. Eng. Series; McGraw-Hill: New York, 1980.
26. Churlaud, R.; Frey, U.; Metz, F.; Merbach, A. E. Inorg. Chem. 2000, 39, 304.
27. Hayden, B. E.; King, A.; Newton, M. A.; Yoshikawa, N. J. Mol. Catal. A 2001, 167, 33.
28. See, for instance: Anderson, J. A.; Millar, G. J.; Rochester, C. H. J. Chem. Soc., Faraday Trans 1990, 86, 571.
29. Chafik, T.; Kondarides, D. I.; Verykios, X. E. J. Catal 2000, 190, 446.
30. 2 species with and without Rh-Cl coordination, were tested. All yielded appreciably higher R factors (> 10%) than the nitrosyl model presented here.