Iron(II) and ruthenium(II) complexes containing bidentate, tied-back diphosphonite ligands. X-ray structure of cis-FeMe2[(-OCH2CEt2CH2O-) PCH2CH2P (-OCH2CEt2CH2O-)]2

Organometallics

Volumn 20, Issue 11, 2001, Pages 2413-2416

  Fang, Xinggao ^a   Scott, Brian L ^a   Watkin, John G ^a   Kubas, Gregory J ^a  

^a LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL SHIFTS; DIPHOSPHONITE; DIPHOSPHONITE LIGAND; STERIC;

COMPLEXATION; IRON COMPOUNDS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RUTHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

ORGANOMETALLICS;

EID: 0035963236     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om001025+     Document Type: Article

References (25)

1. For selected recent examples, see for Ru(II): (a) Schlaf, M.; Lough, A. J.; Morris, R. H. Organometallics 1997, 16, 1253.
2. (b) Rocchini, E.; Mezzetti, A; Ruegger, H.; Burckhardt, U.; Gramlich, V.; Del Zotto, A.; Martinuzzi, P.; Rigo, P. Inorg. Chem. 1997, 36, 711.
3. (c) Six, C.; Gabor, B.; Gorls, H.; Mynott, R.; Philipps, P.; Leitner, W. Organometallics 1999, 18, 3316.
4. (d) Stoop, R. M.; Bauer, C.; Setz, P.; Worle, M.; Wong, T. Y. H.; Mezzetti, A.; Organometallics 1999, 18, 5691.
5. (e) Martelletti, A.; Gramlich, V.; Zurcher, F.; Mezzetti, A. New J. Chem. 1999, 23, 199.
6. For Fe(II): (f) Landau, S. E.; Morris, R. H.; Lough, A. J. Inorg. Chem. 1999, 38, 6060.
7. (g) Bennett, M. A.; Ditzel, E. J.; Hunter, A. D.; Khan, K.; Kopp, M. R.; Neumann, H.; Robertson, G. B.; Zeh, H. J. Chem. Soc., Dalton Trans. 2000, 1733.
8. (a) Fang, X.-G.; Vincent, J. H.; Scott, B. L.; Kubas, G. J. J. Organomet. Chem. 2000, 609, 95.
9. (b) Fang, X.-G.; Scott, B. L.; John, K. D.; Kubas, G. J. Organometallics 2000, 19, 4141.
10. Squires, M. E.; Sardellas, D. J.; Kool, L. B. Organometallics 1994, 13, 2970.
11. (a) Mezzetti, A.; Del Zotto, A.; Rigo, P.; Pahor, N. B. J. Chem. Soc., Dalton Trans. 1989, 1045.
12. (b) Chin, B.; Lough, A. J.; Morris, R. H.; Schweitzer, C. T.; D'Agostino, C. Inorg. Chem. 1994, 33, 6278.
13. 2-insoluble polymeric species.
14. Field, L. D.; Thomas, L. P.; Hambley, T. W.; Turner, P. Inorg. Chem. 1998, 37, 612 and references therein.
15. Girolami, G. S.; Wilkinson, G.; Galas, A. M. R.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1985, 1345.
16. 2) was mentioned: Wong, W.-K.; Chiu, K.; Wilkinson, G.; Howes, A. J.; Motevalli, M.; Hursthouse, M. B. Polyhedron 1985, 4, 603. However, no meaningful geometrical parameters were reported because of extensive orientational disorder of the molecule.
17. Kisko, J. L.; Hascall, T.; Parkin. G. J. Am. Chem. Soc. 1998, 120, 10561.
18. (a) Guggenberger, L. J.; Titus, D. D.; Flood, M. T.; Marsh, R. E.; Orio, A. A.; Gray, H. B. J. Am. Chem. Soc. 1972, 94, 1135.
19. (b) Albertin, G.; Orio, A. A.; Calogero, S.; Sipio, L. D.; Pelizzi, G. Acta Crystallogr. 1976, B32, 3023.
20. Hudson, B.; Webster, D. E.; Wells, P. B. J. Chem. Soc., Dalton Trans. 1972, 1204.
21. Strohmeier, W.; Siefert, F. Chem. Ber. 1961, 94, 2356.
22. SMART Version 4.210; Bruker Analytical X-ray Systems, Inc., 6300 Enterprises Lane, Madison, WI 53719, 1996.
23. SAINT Version 4.05; Bruker Analytical X-ray Systems, Inc., Madison, WI 53719, 1996.
24. Sheldrick, G. M. SADABS; University of Göttingen, Göttingen, Germany, 1996.
25. SHELXTL NT Version 5.10; Bruker Analytical X-ray Instrumentals, Inc., Madison, WI 53719, 1997.