SbF5-mediated reactions of oxafluorodiazirines

Organic Letters

Volumn 3, Issue 15, 2001, Pages 2305-2308

  Moss, Robert A ^a   Fedé, Jean Marie ^a   Yan, Shunqi ^b  

^a RUTGERS UNIVERSITY   (United States)

^b NATIONAL CANCER INSTITUTE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIMONY; DIAZOMETHANE; DRUG DERIVATIVE; FLUORIDE; FLUORINATED HYDROCARBON;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY;

ANTIMONY; DIAZOMETHANE; FLUORIDES; HYDROCARBONS, FLUORINATED; MODELS, MOLECULAR;

EID: 0035954863     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol010091k     Document Type: Article

References (22)

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18. DPM and TPM were verified by GC-spiking experiments with authentic samples. Two unidentified components (5% and 8% of the total GC integrals) were also present.
19. Yan S.; Sauers, R. R.; Moss. R. A. Org. Lett. 1999, 1, 1603.
20. 5/C.
21. (a) All optimizations utilized Gaussian98, Revision A.7, with default convergence criteria; Gaussian. Inc.: Pittsburgh, PA, 1998. The LANL2DZ basis set was used for Sb. (b) DFT calculations used Becke's three-parameter hybrid method with the LFP correlation functional: Becke, A. D. J. Chem. Phys. 1993, 98, 5648.
22. 5-mediated process is at least 12.7 kcal/mol less endothermic.