Specific solvent effects on the structure and reaction dynamics of benzophenone ketyl radical

Journal of Physical Chemistry A

Volumn 105, Issue 42, 2001, Pages 9628-9636

  Kawai, Akio ^a   Hirakawa, Màkoto ^a   Abe, Toyohiko ^a   Obi, Kinichi ^a,b   Shibuya, Kazuhiko ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b JAPAN WOMEN'S UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; CONFORMATIONS; FREE RADICALS; PARAMAGNETIC RESONANCE; REACTION KINETICS; SOLVENTS; STRUCTURE (COMPOSITION); THERMODYNAMICS;

COMPLEX FORMATION;

AROMATIC COMPOUNDS;

EID: 0035950799     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0121320     Document Type: Article

References (41)

1. (a) Obi, K.; Yamaguchi, H. Chem. Phys. Lett. 1978, 54, 448.
2. (b) Takeda, K.; Kajii, Y.; Shibuya, K.; Obi, K. J. Photochem. Photobiol., A Chem. 1998, 115, 109.
3. Nagarajan, V.; Fessenden, R. W. Chem. Phys. Lett. 1984, 112, 207.
4. Hiratsuka, H.; Yamazaki, Y.; Maekawa, Y.; Hikida, T.; Mori, Y. J. Phys. Chem. 1986, 90, 774.
5. (a) Johnston, L. J.; Lougnot, D. J.; Wintgens, V.; Scaiano, J. C. J. Am. Chem. Soc. 1988, 110, 518.
6. (b) Redmond, R. W.; Scaiano, J. C.; Johnson, L. J. J. Am. Chem. Soc. 1990, 112, 398.
7. (a) Baumann, H.; Merckel, C.; Timpe, H.-J.; Graness, A.; Kleinschmidt, J.; Gould, I. R.; Turro, N. J.; Chem. Phys. Lett. 1984, 103, 497.
8. (b) Baumann, H.; Schumacher, K. P.; Timpe, H.-J.; Rehák, V.; Chem. Phys. Lett. 1982, 89, 315.
9. (c) Adam, W.; Oestrich, R. S.; Chem. Ber. 1992, 125, 2463.
10. (a) Terazima, M.; Okamoto, K.; Hirota, N. J. Phys. Chem. 1993, 97, 13387.
11. (b) Ukai, A.; Hirota, N.; Terazima, M. Chem. Phys. Lett. 2000, 319, 427.
12. (a) Wilson, R. J. Chem. Soc. (B) 1968, 84.
13. (b) Davidson, R. S.; Wison, R. J. Chem. Soc. (B) 1970, 71.
14. Kajii, Y.; Itabashi, H.; Shibuya, K.; Obi, K. J. Phys. Chem. 1992, 96, 7244.
15. Abe, T.; Kawai, A.; Kajii, Y.; Shibuya, K.; Obi, K. J. Phys. Chem. A 1999, 103, 1457.
16. Kawai, A.; Aoki, A.; Kobori, Y.; Obi, K. J. Phys. Chem. 1996, 100, 10021.
17. Kawai, A.; Kobori, Y.; Obi, K. Chem. Phys. Lett. 1993, 215, 203.
18. The molecular plane of BPK means the plane defined by three carbon and one oxygen atoms within the C-C(OH)-C moiety of BPK.
19. Kajii, Y.; Fujita, M.; Hiratuska, H.; Obi, K.; Mori, Y.; Tanaka, I. J. Phys. Chem. 1987, 91, 2791.
20. Miyasaka, H.; Mataga, N. Bull. Chem. Soc. Jpn. 1990, 63, 131.
21. (a) Miyasaka, H.; Nagata, T.; Kin, M.; Mataga, N. J. Phys. Chem. 1992, 96, 8060.
22. (b) Miyasak, H.; Morita, K.; Kamada, K.; Mataga, N. Bull. Chem. Soc. Jpn. 1990, 63, 3385.
23. Devadoss, C.; Fessenden, R. W. J. Phys. Chem. 1991, 95, 7253.
24. (a) Onsager, L. J. Am. Chem. Soc. 1936, 58, 1486.
25. (b) Wilson, J. N. Chem. Rev. 1939, 25, 377.
26. (c) McRae, E. G. J. Phys. Chem. 1957, 61, 562.
27. Shrestha, N. K.; Yagi, E. J.; Takalori, Y.; Kawai, A.; Kajii, Y.; Shibuya, K.; Obi, K. J. Photochem. Photobiol., A Chem. 1998, 116, 179.
28. For example; Muus, L. T.; Atkins, P. W.; McLauchlan, K. A.; Pedersen, J. B. Chemically Induced Magnetic Polarization; Reidel: Dordrecht, 1977.
29. (a) Miyagawa, K.; Murai, H.; I'Haya, Y. J. Chem. Phys. Lett. 1985, 118, 140.
30. (b) Miyagawa, K.; I'Haya, Y. J.; Murai, H. Nippon Kagaku Kaishi 1989, 8, 1358.
31. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Gill, P. M. W.; Johnson, B. G.; Robb, M. A.; Cheeseman, J. R.; Keith, T.; Petersson, G. A.; Montgomery, J. A.; Raghavachari, K.; Al-Laham, M. A.; Zakrzewski, V. G.; Ortiz, J. V.; Foresman, J. B.; Cioslowski, J.; Stefanov, B. B.; Nanayakkara, A.; Challacombe, M.; Peng, C. Y.; Ayala, P. Y.; Chen, W.; Wong, M. W.; Andres, J. L.; Replogle, E. S.; Gomperts, R.; Martin, R. L.; Fox, D. J.; Binkley, J. S.; Defrees, D. J.; Baker, J.; Stewart, J. P.; Head-Gordon, M. H.; Gonzalez, C.; Pople, J. A. Gaussian 94; Gaussian, Inc.: Pittsburgh, PA, 1995.
32. (a) Takeshita, T.; Hirota, N. J. Chem. Phys. 1969, 51, 2146.
33. (b) Bernardi, F.; Guerra, M.; Pedulli, G. F. J. Phys. Chem. 1974, 78, 2144.
34. Wada, S.; Matsushita, Y.; Obi, K. J. Phys. Chem. A 1997, 101, 2423.
35. Atherton, N. M. Principles of Electron Spin Resonance; Ellis Horwood Limited: Chichester, U.K., 1993.
36. Spernol, von A.; Wirtz, K. Z. Natureforsch. 1953, 8a, 522.
37. Fukui, T.; Shimamori, H. Unpublished data measured by a time-resolved microwave dielectric absorption method.
38. For the experimental method, see Shimamori, H.; Uegaito, H.; Houdo, K. J. Phys. Chem. 1991, 95, 7664.
39. CRC Handbook of Chemistry and Physics, 1988-1989, 69th ed.; Weast, R. C., Ed.; CRC Press: Boca Raton, FL, 1988.
40. (a) Murove, S. L.; Charmichael, I.; Hug, G. L. Handbook of Photochemistry; Marcel Dekker Inc.: New York, 1993.
41. (b) CRC Handbook of Chemistry and Physics, 1995-1996, 76th ed.; Lide, D. R., Ed.; CRC Press: Boca Raton, FL, 1995.