Phenyltrichlorogermane synthesis by the reaction of chlorobenzene and the dichlorogermylene intermediate formed from elemental germanium and tetrachlorogermane

Organometallics

Volumn 20, Issue 26, 2001, Pages 5583-5585

  Okamoto, Masaki ^a   Asano, Takuya ^a   Suzuki, Eiichi ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHLOROBENZENE; DICHLOROGERMYLENE; PHENYLTRICHLOROGERMANE; TETRACHLOROGERMANE;

CHEMICAL BONDS; CHLORINE COMPOUNDS; FLOW OF FLUIDS; GERMANIUM; PYROLYSIS; SYNTHESIS (CHEMICAL);

GERMANIUM COMPOUNDS;

EID: 0035945420     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010761q     Document Type: Article

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26. The reaction of elemental germanium (6.88 mmol) and chlorobenzene (200 mmol) with copper(I) chloride catalyst (2.27 mmol) was carried out in a 120 mL autoclave at 350°C for 60 h. The germanium conversion was 76%, and the selectivities for phenyltrichlorogermane, diphenyldichlorogermane, and triphenylchlorogermane were 53%, 45%, and 2%, respectively.
27. 2), whose reaction with chlorobenzene afforded dichlorobenzenes and chlorine again (eq 8). The effect of the chain of these reactions on the germanium conversion is small because the reaction of 4 mol of hydrogen chloride gives 1 mol of germanium consumed and a part of hydrogen chloride remained in the reaction mixture.