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1,2-Olefins in polybutadiene are reduced faster than 1,4-olefins and cis-1,4 units faster than trans-1,4 units.
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Examples of tandem ROMP-hydrogenation or ADMET-hydrogenation via 1: (a) McLain, S. J.; McCord, E. F.; Arthur, S. D.; Hauptman, E.; Feldman, J.; Nugent, W. A.; Johnson, L. K.; Mecking, S.; Brookhart, M. Polym. Mater. Sci. Eng. 1997, 76, 246.
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At least 5 equiv required; see the Supporting Information.
-
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30
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0011409833
-
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note
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2 and THF fully dissolve these polymer substrates. The limitations of THF are discussed above.
-
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32
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0000000121
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3 reaction does occur, however, it clearly does not compete with initial abstraction of HCl from 3/4 to yield 5. The latter reaction is immediate and quantitative.
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34
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