Kinetics of methylene chloride hydrolysis and the salt effect under hydrothermal conditions

Industrial and Engineering Chemistry Research

Volumn 40, Issue 4, 2001, Pages 1026-1031

  Oshima, Yoshito ^a   Bijanto, Budianto ^a   Koda, Seiichiro ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

DICHLOROMETHANE; SODIUM CHLORIDE; TITANIUM; WATER;

ARTICLE; CORROSION; DIELECTRIC CONSTANT; HYDROLYSIS; KINETICS; REACTION ANALYSIS; SALINITY; TEMPERATURE SENSITIVITY; THERMODYNAMICS;

EID: 0035925255     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie0005598     Document Type: Article

References (14)

1. Marrone, P. A.; Arias, T. A.; Peters, W. A.; Tester, J. W. Solvation Effects on Kinetics of Methylene Chloride Reaction in Sub- and Supercritical Water: Theory, Experiment, and ab initio Calculations. J. Phys. Chem. A 1998, 102, 7013.
2. Marrone, P. A.; Gschwend, P. M.; Swallow, K. C.; Peters, W. A.; Tester, J. W. Product Distribution and Reaction Pathways for Methylene Chloride Hydrolysis and Oxidation under Hydrothermal Conditions. J. Supercrit. Fluids 1998, 12, 239.
3. Tester, J. W.; Marrone, P. A.; DiPippo, M. M.; Sako, K.; Reagan, M. T.; Arias, T.; Peters, W. A. Chemical Reactions and Phase Equilibria of Model Halocarbons and Salts in Sub- and Supercritical Water (200-300 bar, 100-600°C). J. Supercrit. Fluids 1998, 13, 225.
4. Salvatierra, D.; Taylor, J. D.; Marrone, P. A.; Tester, J. W. Kinetic Study of Hydrolysis of Methylene Chloride from 100 to 500°C. Ind. Eng. Chem. Res. 1999, 38, 4162.
5. Thammanayakatip, C.; Oshima Y.; Koda, S. Inhibition Effect in Supercritical Water Oxidation of Hydroquinone. Ind. Eng. Chem. Res. 1998, 37, 2061.
6. Krammer, P.; Vogel, H. Hydrolysis of Esters in Subcritical and Supercritical Water. J. Supercrit. Fluids 2000, 16, 189.
7. Huppert, G. L.; Wu, B. C.; Townsend, S. H.; Klein, M. T.; Paspek, S. C. Hydrolysis in Supercritical Water: Identification and Implications of a Polar Transition State. Ind. Eng. Chem. Res. 1989, 28, 161.
8. Torry, L. A.; Kaminsky, R.; Klein, M. T.; Klotz, M. R. The Effect of Salts on Hydrolysis in Supercritical and Near-critical Water: Reactivity and Availability. J. Supercrit. Fluids 1992, 5, 163.
9. Penninger, J. M. L.; Kerste, R. J. A.; Baur, H. C. L. Hydrolysis of Diphenyl ether in Supercritical Water Effects of Dissolved NaCl. J. Supercrit. Fluids 2000, 17, 215.
10. Driesner, T.; Seward, T. M.; Tironi, I. G. Molecular Dynamics Simulation Study of Ionic Hydration and Ion Association in Dilute and 1 Molar Aqueous Sodium Chloride Solutions from Ambient to Supercritical Conditions. Geochim. Cosmochim. Acta 1998, 62, 3095.
11. Benson, S. W. The Foundations of Chemical Kinetics; McGraw-Hill Book Co.: New York, 1960; pp 521-528.
12. Quint, J. R.; Wood, R. H. Thermodynamics of a Charged Hard-sphere Ion in a Compressible Dielectric Fluid. 2. Calculation of the Ion - solvent Pair Correlation Function, the Excess Solvation, the Water-like Fluid above the Critical Point. J. Phys. Chem. 1985, 89, 380.
13. Uematsu, M.; Franck, E. U. Static Dielectric Constant of Water and Steam. J. Phys. Chem. Ref. Data 1980, 9, 1291.
14. Haar, L.; Gallagher, J. S.; Kell, G. S. NBS/NRC Steam Tables; Hemisphere Pub. Co.: Washington, DC, 1984.