Methylcyclohexane tansformation over HFAU, HBEA, and HMFI zeolites: I. Reaction scheme and mechanisms

Industrial and Engineering Chemistry Research

Volumn 40, Issue 4, 2001, Pages 1032-1041

  Cerqueira, Henrique S ^a   Mihindou Koumba, Pierre C ^a   Magnoux, Patrick ^a   Guisnet, Michel ^a  

^a UNIVERSITÉ DE POITIERS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; AROMATIC COMPOUND; CYCLOHEXANE DERIVATIVE; CYCLOPENTANE DERIVATIVE; FAUJASITE; HBEA 15; HBEA 26; HFAU 15; HMFI 15; HYDROGEN; UNCLASSIFIED DRUG; ZEOLITE;

ARTICLE; CALCULATION; CHEMICAL MODIFICATION; KINETICS; MOLECULAR MODEL; REACTION ANALYSIS; STRUCTURE ANALYSIS;

EID: 0035925249     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie000730f     Document Type: Article

References (9)

1. Corma, A.; Agudo, A. L. Isomerization, Dehydrogenation and Cracking of Methylcyclohexane over HNaY Zeolites. React. Kinet. Catal. Lett. 1981, 16, 253.
2. Lin, L.; Gnep, N. S.; Guisnet, M. Comparative Study of Alkanes and of Cycloalkanes on USHY Reaction Mechanisms. Proceedings of the American Chemical Society Division of Petroleum Chemistry, Miami, FL, 1989; p 687.
3. Abbot, J. Active Sites and Intermediates for Isomerization and Cracking of Cyclohexane on HY. J. Catal. 1990, 123, 383.
4. Mostad, H. B.; Riis, T. U.; Ellestad, O. H. Shape Selectivity in Y-Zeolites. Catalytic Cracking of Decalin-Isomers in Fixed Bed Microreactors. Appl. Catal. 1990, 58, 105.
5. Corma, A.; Mocholi, F.; Orchillés, V.; Koermer, G. S.; Madon, R. J. Methylcyclohexane and Methylcyclohexene Cracking over Zeolite Y Catalysts. Appl. Catal. 1991, 67, 307.
6. Sousa-Aguiar, E. F.; Mota, C. J. A.; da Silva, M. P.; Valle, M. L. M.; da Silva, D. F. Catalytic Cracking of Decalin Isomers over REHY-Zeolites with Different Crystallite Sizes. J. Mol. Catal. 1996, 104, 267.
7. de la Puente, G.; Sedran, U. Conversion of Methylcyclopentane on Rare Earth Exchanged Y Zeolite FCC Catalysts. Appl. Catal. 1996, 144, 147.
8. Scofield, C. F.; Benazzi, E.; Cauffriez, H.; Marcilly, C. Methylcyclohexane Conversion to Light Olefins. Braz. J. Chem. Eng. 1998, 15, 218.
9. Cerqueira, H. S.; Magnoux, P.; Martin, D.; Guisnet, M. Effect of Contact Time on the Nature and Location of Coke during Methylcyclohexane Transformation over a USHY Zeolite. Stud. Surf. Sci. Catal. 1999, 126, 105.