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note
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1 the spin wave function(s) for a low-lying singlet state or states, and cc and α′ mixing coefficients which depend on the magnitude of the spin-orbit constant and the triplet-singlet energy gap. On the basis of this analysis, the magnitude of V for Förster transfer depends on the product αα′ and the extent of singlet character in both the donor and acceptor excited states.
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0011368471
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note
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-1 for energy transfer, A difference between the two of this magnitude would not be surprising given the difference in the nature of the chemical links to the surface, Scheme 1. For energy migration there are phosphonate-phosphonate surface links and for energy transfer phosphonate-carboxylate links.
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