Redox kinetics in monolayers on electrodes: Electron transfer is sluggish for ferrocene groups buried within the monolayer interior

Journal of Physical Chemistry B

Volumn 105, Issue 37, 2001, Pages 8739-8745

  Sumner, James J ^a   Creager, Stephen E ^a  

^a CLEMSON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ION TRANSPORT;

ELECTRODES; ELECTROLYTES; ELECTRON TRANSPORT PROPERTIES; INTERFACES (MATERIALS); MONOLAYERS; OXIDATION; RATE CONSTANTS; REDUCTION; SOLUTIONS; THERMODYNAMIC PROPERTIES;

REDOX REACTIONS;

EID: 0035922533     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp011229j     Document Type: Article

References (36)

1. Molecular Design of Electrode Surfaces; Techniques of Chemistry Series; Murray, R.W., Ed.; John Wiley & Sons: New York, 1992; Vol. 22.
2. Elliott, C.M.; Redepenning, J.G.; Balk, E.M. J.f Electroanal. Chem. 1986, 213, 203-215.
3. Elliott, C.M.; Redepenning, J.G.; Balk, E.M. J. Am. Chem. Soc. 1985, 107, 8302-8304.
4. Jernigan, J.C.; Chidsey, C.E.D.; Murray, R.W. J. Am. Chem. Soc. 1985, 107, 2824-2826.
5. Jernigan, J.C.; Murray, R.W. J. Phys. Chem. 1987, 91, 2030-2032.
6. Saveant, J.M. J.f Electroanal. Chem. 1988, 242, 1-21.
7. Saveant, J.M. J. Phys. Chem. 1988, 92, 1011-1013.
8. Rowe, G.K.; Creager, S.E. J. Phys. Chem. 1994, 98, 5500-5507.
9. Rowe, G.K.; Creager, S.E. Langmuir 1991, 7, 2307-2312.
10. Creager, S.E.; Rowe, G.K. J. Electroanal. Chem. 1997, 420, 291-299.
11. Creager, S.E.; Rowe, G.K. Anal. Chim. Acta 1991, 246, 233-239.
12. Uosaki, K.; Sato, Y.; Kita, H. Langmuir 1991, 7, 1510-1514.
13. Shimazu, K.; Yagi, I.; Sato, Y.; Uosaki, K. J. Electroanal. Chem. 1994, 372, 117-124.
14. Redepenning, J.; Tunison, H.M.; Finldea, H.O. Langmuir 1993, 9, 1404-1407.
15. Redepenning, J.; Flood, J.M. Langmuir 1996, 12, 508-512.
16. Pilloud, D.L.; Chen, X.X.; Dutton, P.L.; Moser, C.C. J. Phys. Chem. B 2000, 104, 2868-2877.
17. John, S.A.; Kitamura, F.; Nanbu, N.; Tokuda, K.; Ohsaka, T. Langmuir 1999, 15, 3816-3822.
18. Zhang, J.J.; Lever, A.B.P.; Pietro, W.J. J. Chem. Soc., Faraday Trans. 1997, 93, 3355-3362.
19. Ohtani, M.; Kuwabata, S.; Yoneyama, H. Anal. Chem. 1997, 69, 1045-1053.
20. Forster, R.J.; Faulkner, L.R. J. Am. Chem. Soc. 1994, 116, 5444-5452.
21. Acevedo, D.; Abruna, H.D. J. Phys. Chem. 1991, 95, 9590-9594.
22. Smith, C.P.; White, H.S. Anal. Chem. 1992, 64, 2398-2405.
23. Fawcett, W.R. J. Electroanal. Chem. 1994, 378, 117-124.
24. Andreu, R.; Calvente, J.J.; Fawcett, W.R.; Molero, M. J. Phys. Chem. B 1997, 101, 2884-2894.
25. Honeychurch, M.J.; Rechnitz, G.A. Electroanalysis 1998, 10, 285-293.
26. Campbell, D.J.; Herr, B.R.; Hulteen, J.C.; Van Duyne, R.P.; Mirkin, C.A. J. Am. Chem. Soc. 1996, 118, 10211-10219.
27. Creager, S.E.; Rowe, G.K. J. Electroanal. Chem. 1994, 370, 203.
28. Creager, S.E.; Wooster, T.T. Analy. Chem. 1998, 70, 4257-4263.
29. Sumner, J.J.; Weber, K.S.; Hockett, L.A.; Creager, S.E. J. Phys. Chem. B 2000, 104, 7449-7454.
30. Creager, S.; Yu, C.J.; Bamdad, C.; O'Connor, S.; MacLean, T.; Lam, E.; Chong, Y.; Olsen, G.T.; Luo, J.; Gozin, M.; Kayyem, J.F. J. Am. Chem. Soc. 1999, 121, 1059-1064.
31. Sumner, J.J.; Creager, S.E. J. Am. Chem. Soc. 2000, 122, 11914-11920.
32. Brevnov, D.A.; Finklea, H.O. J. Electrochem. Soc. 2000, 147, 3461-3466.
33. Nahir, T.M.; Bowden, E.F. J. Electroanal. Chem. 1996, 410, 9.
34. O'Connor, S.D.; Olsen, G.T.; Creager, S.E. J. Electroanal. Chem. 1999, 466, 197-202.
35. Li, J.; Schuler, K.; Creager, S.E. J. Electrochem. Soc. 2000, 147, 4584-4588.
36. Marcus, R.A. J. Phys. Chem. B 1998, 102, 10071-10077.