Direct experimental determination of the energy barriers for methyl cation transfer in the reactions of methanol with protonated methanol, protonated acetonitrile, and protonated acetaldehyde: A low pressure FTICR study

Journal of Physical Chemistry A

Volumn 105, Issue 15, 2001, Pages 3816-3824

  Fridgen, Travis D ^a   Keller, Jonathan D ^a   McMahon, Terry B ^a  

^a UNIVERSITY OF WATERLOO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CATION TRANSFER;

ACETONITRILE; ACTIVATION ENERGY; CHARGE TRANSFER; COMPLEXATION; DIMERS; ENTHALPY; ENTROPY; FOURIER TRANSFORM INFRARED SPECTROSCOPY; ISOMERIZATION; MASS SPECTROMETRY; METHANOL; POSITIVE IONS; PRESSURE EFFECTS; PROTONS;

RATE CONSTANTS;

EID: 0035912416     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0043165     Document Type: Article

References (39)

1. Organic Chemistry, 6th ed.; Morrison, R. T., Boyd, R. N., Eds.; Prentice Hall: Englewood Cliffs, NJ, 1992.
2. Hall, D. G.; Gupta, C.; Morton, T. H. J. Am. Chem. Soc. 1981, 103, 2416.
3. McMahon, T. B.; Beauchamp, J. L. J. Phys. Chem. 1977,81,593.
4. Kleingeld, J. C.; Nibbering, N. M. M. Org. Mass Spectrom. 1982, 17, 136.
5. Karpas, Z.; Meot-Ner, M. J. Phys. Chem. 1989, 93, 1859.
6. Meot-Ner, M.; Karpas, Z. J. Phys. Chem. 1986, 90, 2206.
7. Fridgen, T. D.; McMahon, T. B. J. Am. Chem. Soc., in press.
8. Herman, J. A.; Xu, G.; Herman, K.; McMahon, T. B. Int. J. Mass Spectrom. Ion Processes 1992, 113, 143.
9. Szulejko, J. E.; Fisher, J. J.; McMahon, T. B.; Wronka, J. Int. J. Mass Spectrom. Ion Processes 1988, 83, 147.
10. Wilson, P. F.; McEwan, M. J.; Meot-Ner, M. Int. J. Mass Spectrom. Ion Processes 1994, 132, 149.
11. McMahon, T. B.; Heinis, T.; Nicol, G.; Hovey, J. K.; Kebarle, P. J. Am. Chem. Soc. 1988,110, 7591.
12. Deakyne, C. A.; Meot-Ner, M. J. Phys. Chem. 1990, 94, 232.
13. Concise descriptions and application of the various methods have been consolidated in: (a) Techniques for the Study of Ion-Molecule Reactions; Farrar, J. M., Saunders, W. H., Jr., Eds.; John Wiley & Sons: Toronto, 1988.
14. And (b) Advances in Gas-Phase Ion Chemistry; Adams, N. G., Babcock, L. M., Eds.; JAI Press Inc.: Greenwich, CT, 1996.
15. As well, there are four review articles by the following sets of authors: (a) Bowers, M. T.; Kemper, P. R.; van Koppen, P.; Wyttenbach, T.; Carpenter, C. J.; Weis, P.; Gidden, J.;
16. (b) McMahon, T. B.;
17. Luis, J.; Abboud, M.; Notario, R.;
18. Baer, T.; Lafleur, R.; Mazyar, O. In Energetics of Stable Molecules and Reactive Intermediates', Minas da Piedade, M. E., . Ed.; Kluwer Academic Press: Boston, 1999.
19. NIST Chemistry WebBook, NIST Standard Reference Database Number 69; Mallard, W. G., Linstrom, P. J., Eds.; National Institute of Standards and Technology: Gaithersburg, MD, February 2000; 20899 (http://webbook.nist.gov).
20. Refaey, K. M. A.; Chupka, W. A. J. Chem. Phys. 1968,48, 5205.
21. Booze, J. A.; Baer, T. J. Phys. Chem. 1992, 96, 5710.
22. Booze, J. A.; Baer, T. J. Phys. Chem. 1992, 96, 5715.
23. Mayer, P. M. J. Phys. Chem. A 1999, 103, 3687.
24. Ochran, R. A.; Annamalai, A.; Mayer, P. M. J. Phys. Chem. A 2000,104, 8505.
25. Gaussian 98, Revision A.7; Frisch, M. J., Trucks, G. W., Schlegel, H. B., Scuseria, G. E., Robb, M. A., Cheeseman, J. R., Zakrzewski, V. G., Montgomery, J. A., Jr., Stratmann, R. E., Burant, J. C., Dapprich, S., Millam, J. M., Daniels, A. D., Kudin, K. N., Strain, M. C., Farkas, O., Tomasi, J., Barone, V., Cossi, M., Cammi, R., Mennucci, B., Pomelli, C., Adamo, C., Clifford, S., Ochterski, J., Petersson, G. A., Ayala, P. Y., Cui, Q., Morokuma, K., Malick, D. K., Rabuck, A. D., Raghavachari, K., Foresman, J. B., Cioslowski, J., Ortiz, J. V., Baboul, A. G., Stefanov, B. B., Liu, G., Liashenko, A., Piskorz, P., Komaromi, I., Gomperts, R., Martin, R. L:, Fox, D. J., Keith, T., Al-Laham, M. A., Peng, C. Y., Nanayakkara, A., Gonzalez, C, Challacombe, M., Gill, P. M. W., Johnson, B., Chen, W., Wong, M. W., Andres, J. L., Gonzalez, C., Head-Gordon, M., Replogle, E. S., Pople, J. A., Eds.; Gaussian, Inc.: Pittsburgh, PA, 1998.
26. Vogt, J.; Beauchamp, J. L. J. Am. Chem. Soc. 1975, 97, 6682.
27. Bass, L. M.; Cates, R. D.; Jarrold, M. F.; Kirchner, N. J.; Bowers, M. T. J. Am. Chem. Soc. 1983, 105, 7024.
28. Morris, R. A.; Viggiano, A. A.; Paulson, J. F.; Henchman, M. J. J. Am. Chem. Soc. 1991, 113, 5932.
29. Bouchoux, G.; Choret, N. Rapid Commun. Mass Spectrom. 1997, //, 1799.
30. Raghavachari, K.; Chandrasekhar, J.; Burnier, R. C. J. Am. Chem. Soc. 1984,106, 3124.
31. (a) Meot-Ner, M. J. Am. Chem. Soc. 1992,114, 3312.
32. (b) Larson, J. W.; McMahon, T. B. J. Am. Chem. Soc. 1982, 104, 6255.
33. Dolnikowski, G. G.; Heath, T. G.; Watson, J. T.; Scrivens, J. H.; Rolando, C. H. J. Am. Chem. Soc. Mass Spectrom. 1990, 1, 481.
34. Tzeng, W. B.; Wei, S.; Castleman, A. W., Jr. Chem. Phys. Lett. 1990, 168, 30.
35. König, S.; Kofel, P.; Reinhard, H.; Sägesser, M.; Schlunegger, U. P. Org. Mass Spectrom. 1993, 28, 1101.
36. Fridgen, T. D.; McMahon, T. B. J. Phys. Chem. A 2001,105,1011.
37. Graul, S. T.; Squires, R. R. Int. J. Mass Spectrom. Ion Processes 1987, 81, 183.
38. Dang, T. T.; Bierbaum, V. M. Int. J. Mass Specrom. Ion Processes 1992, 117, 65.
39. McMahon, T. B., unpublished results.