Rhodium-catalyzed addition of phenylmethyldifluorosilane to aldehydes

Organometallics

Volumn 20, Issue 6, 2001, Pages 1036-1037

  Oi, Shuichi ^a   Moro, Mitsutoshi ^a   Inoue, Yoshio ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYL COMPOUNDS; PHENYLMETHYLDIFLUOROSILANE; PHENYLRHODIUM; TRANSMELATION;

ALCOHOLS; ALDEHYDES; CATALYSIS; CHEMICAL BONDS; FLUORINE COMPOUNDS; REACTION KINETICS; RHODIUM COMPOUNDS; SILANES; SILICATES;

ORGANOMETALLICS;

EID: 0035911985     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0009684     Document Type: Article

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14. 2 atmosphere in a sealed Schlenk tube. The reaction was quenched by adding a small amount of water and then stirred for 1 h. After the solvent was evaporated in vacuo, the residue was purified by silica gel chromatography eluting with hexanes-ethyl acetate (5:1) to give the product alcohol 3.
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