β-Selective glycosylations with masked D-mycosamine precursors

Organic Letters

Volumn 3, Issue 21, 2001, Pages 3393-3396

  Packard, Garrick K ^a   Rychnovsky, Scott D ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIINFECTIVE AGENT; CHOLESTEROL; HEXOSAMINE; MACROLIDE; MYCOSAMINE;

ARTICLE; CHEMISTRY; GLYCOSYLATION; SYNTHESIS;

ANTI-BACTERIAL AGENTS; CHOLESTEROL; GLYCOSYLATION; HEXOSAMINES; MACROLIDES;

EID: 0035909642     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol016617i     Document Type: Article

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27. The TBS protecting group is necessary since both C4 acetates and benzoates are eliminated upon oxidation of the C2 alcohol.
28. 2; therefore, following an aqueous workup, it is used directly in the next step.