Thermodynamics of the hydrophobic effect. II. Calorimetric measurement of enthalpy, entropy, and heat capacity of aggregation of alkylamines and long aliphatic chains

Biophysical Chemistry

Volumn 93, Issue 1, 2001, Pages 53-65

  Matulis, Daumantas ^a   Bloomfield, Victor A ^a  

^a UNIVERSITY OF MINNESOTA   (United States)

Author keywords

Calorimetric enthalpy; Dodecylammonium chloride; Hydrophobicity; Isothermal titration calorimetry; Thermodynamics of molecular interactions; van't Hoff enthalpy

Indexed keywords

ALIPHATIC AMINE; CARBON; DODECYLAMINE;

AQUEOUS SOLUTION; ARTICLE; CALORIMETRY; DILUTION; DISSOLUTION; ENTHALPY; ENTROPY; HYDROPHOBICITY; MOLECULAR INTERACTION; POTENTIOMETRIC TITRATION; PRIORITY JOURNAL; THERMODYNAMICS; TITRIMETRY;

ALKANES; AMINES; CALORIMETRY; MICELLES; PRECIPITATION; SOLUBILITY; SURFACE-ACTIVE AGENTS; THERMODYNAMICS; WATER;

EID: 0035909442     PISSN: 03014622     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0301-4622(01)00208-3     Document Type: Article

References (21)

1. A simple model of water and the hydrophobic effect
2. Temperature dependence of hydrophobic interactions: a mean force perspective, effects of water density, and nonadditivity of thermodynamic signatures
3. New perspectives on hydrophobic effects
4. Some factors in the interpretation of protein denaturation
5. Direct calorimetric measurement of the heats of solution of some liquid hydrocarbons in water
6. Enthalpies and heat capacities for n-alkan-1-ols in H2O and D2O
7. Enthalpies of dilution of aqueous decyl-, dodecyl-, tetradecyl-, and hexadecyltrimethylammonium bromides at 10, 25, 40, and 55 C
8. Thermodynamics of the hydrophobic effect. I. Coupling of aggregation and pKa shifts in solutions of aliphatic amines
9. Possible origin of differences between van't Hoff and calorimetric enthalpy estimates
10. Significant discrepancies between van't Hoff and calorimetric enthalpies
11. Significant discrepancies between van't Hoff and calorimetric enthalpies. II
12. Significant discrepancies between van't Hoff and calorimetric enthalpies. III
13. Molecular origin of hydration heat capacity changes of hydrophobic solutes - perturbation of water structure around alkanes
14. Thermodynamics of the hydrophobic effect. III. Condensation and aggregation of alkanes, alcohols, and alkylamines
15. Rapid measurement of binding constants and heats of binding using a new titration calorimeter
16. Thermochemical properties of some carboxylic acids, amines and N-substituted amides in aqueous solution