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Volumn 318, Issue 1-2, 2001, Pages 143-151

Electrochemical oxidation of [Cr(CO)4(tmp)] to the low-spin Cr(I) species [Cr(CO)4(tmp)]+ (tmp = 3,4,7,8-tetramethyl-1,10-phenanthroline): An IR, UV-Vis, and EPR spectroelectrochemical and DFT computational study of the accompanying changes in molecular and electronic structure

(6) Farrell, Ian R a Hartl, František b Záliš, Stanislav c Wanner, Matthias d Kaim, Wolfgang d Vlček Jr , Antonín a,c

a QUEEN MARY UNIVERSITY OF LONDON (United Kingdom)

b UNIVERSITY OF AMSTERDAM (Netherlands)

c J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY (Czech Republic)

d UNIVERSITY OF STUTTGART (Germany)

Author keywords

Carbonyl complexes; Chromium complexes; Electrochemistry; Electronic structures; Phenanthroline complexes; Spectroelectrochemistry

Indexed keywords

CARRIER CONCENTRATION; CHEMICAL BONDS; COMPUTATION THEORY; CYCLIC VOLTAMMETRY; DENSITY FUNCTIONAL THEORY; ELECTROCHEMICAL OXIDATION; ELECTROCHEMISTRY; ELECTRON DENSITY MEASUREMENT; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC STRUCTURE; ELECTRONS; GROUND STATE; LIGANDS; NITROGEN COMPOUNDS; POSITIVE IONS; SPECTROELECTROCHEMISTRY;

CARBONYL COMPLEXES; CHROMIUM COMPLEXES; ELECTRON DENSITY REDISTRIBUTIONS; ELECTRONIC GROUND STATE; LOW LYING ELECTRONIC STATE; METAL-CENTERED RADICALS; PHENANTHROLINE COMPLEXES; UV-VIS SPECTROELECTROCHEMISTRY;

CHROMIUM COMPOUNDS;

3,4,7,8 TETRAMETHYL 1,10 PHENANTHROLINE; CARBON DIOXIDE; CARBONYL DERIVATIVE; CATION; CHROMIUM DERIVATIVE; LIGAND; PHENANTHROLINE DERIVATIVE; RADICAL; UNCLASSIFIED DRUG;

ANISOTROPY; ARTICLE; ATOMIC PARTICLE; CALCULATION; CHEMICAL STRUCTURE; CYCLIC POTENTIOMETRY; ELECTROCHEMICAL ANALYSIS; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; HIGH TEMPERATURE; INFRARED RADIATION; OXIDATION; STRUCTURE ANALYSIS; THERMOSTABILITY; ULTRAVIOLET RADIATION;

EID: 0035908226 PISSN: 00201693 EISSN: None Source Type: Journal
DOI: 10.1016/S0020-1693(01)00421-2 Document Type: Article

Times cited : (18)

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