Kinetics and mechanism of cyclohexanol dehydration in high-temperature water

Industrial and Engineering Chemistry Research

Volumn 40, Issue 8, 2001, Pages 1822-1831

  Akiya, N ^a   Savage, P E ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; PROTONS; REACTION KINETICS;

STRIKING EFFECTS;

DEHYDRATION;

1 METHYLCYCLOPENTENE; 3 METHYLCYCLOPENTENE; ACID; CATION; CYCLOHEXANOL; CYCLOHEXENE DERIVATIVE; CYCLOPENTENE DERIVATIVE; OXONIC ACID; UNCLASSIFIED DRUG; WATER;

ALCOHOL; DEHYDRATION; KINETICS;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; DEHYDRATION; DENSITY; HIGH TEMPERATURE; MODEL; PROTON TRANSPORT; REACTION ANALYSIS; SOLVATION; TEMPERATURE DEPENDENCE;

EID: 0035906101     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie000964z     Document Type: Article

References (33)

1. Organic chemical reactions in supercritical water
2. Reactions at supercritical conditions - Applications and fundamentals
3. Transformations of cyclohexane derivatives in supercritical water
4. Classical organic reactions in pure superheated water
5. Mechanism and temperature-dependent kinetics of the dehydration of tert-butyl alcohol in hot compressed liquid water
6. Kinetics and mechanism of isobutene formation from t-butanol in hot liquid water
7. Mechanism and kinetics of the acid-catalyzed dehydration of 1- and 2-propanol in hot compressed liquid water
8. Mechanism and kinetics of the acid-catalyzed formation of ethene and diethyl ether from ethanol in supercritical water
9. Thermophysical properties of fluid systems
10. Influence of water on guaiacol pyrolysis
11. Organic synthesis in subcritical water: Oxidation of alkyl aromatics
12. Acid/base-catalyzed ester hydrolysis in near-critical water
13. Alkylation reactions in near-critical water in the absence of acid catalysts
14. Acceleration of synthetic organic reactions using supercritical water: Noncatalytic Beckmann and Pinacol rearrangements
15. Ion product of water substance, 0-1000 °C, 1-1000 bar: New international formulation and its background
16. Theoretical models and experimental data for reactions between water and protonated alcohols: Substitution and elimination mechanisms
17. Acidity control in alcohol dehydration
18. 3, and relations to double bond shift in olefins
19. Hydration and dehydration by heterogeneous catalysts
20. The mechanism of gas-phase dehydration of cyclohexanol and the methylcyclohexanols catalysed by zirconium phosphate and zirconium phosphite
21. Mechanism of cyclohexanol dehydration catalysed by zirconium phosphate
22. Adsorbed carbocations as transition states in heterogeneous acid-catalyzed transformations of hydrocarbons
23. Carbocations and electrophilic reactions
24. 13C NMR study of tert-butanol interaction with moderately concentrated sulfuric acid
25. New transition-state models and kinetics of elimination reactions of tertiary alcohols over aluminum oxide
26. 2. II. On the mechanism of alcohol dehydration on anatase
27. 2 (Mechanism E1cB)
28. 3
29. A FORTRAN subroutine for solving system of nonlinear algebraic equations