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Volumn 17, Issue 21, 2001, Pages 6569-6576

Effects of packing and orientation on the hydrolysis of ester monolayers on gold

Author keywords

[No Author keywords available]

Indexed keywords

CONTACT ANGLE GONIOMETRY; SINGLE SWEEP VOLTAMMETRY;

EID: 0035900138     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la010590u     Document Type: Article
Times cited : (17)

References (44)
  • 30
    • 0011295273 scopus 로고    scopus 로고
    • note
    • The carboxylic acid groups in a hydrolyzed monolayer in a basic solution are expected to exist in the deprotonated carboxylate form when immersed in 0.5 M KOH. However, the carboxylate groups on the surface appear to partially protonate upon rinsing.
  • 40
    • 0011379037 scopus 로고    scopus 로고
    • note
    • Samples were immersed into the 0.3 M KOH in 33% acetonitrile for a given period of time at room temperature (∼25 °C), withdrawn from the solution, rinsed with water and acetonitrile, blown dry with nitrogen, and the IRS spectrum taken. This process was repeated with the same sample until most of the ester was hydrolyzed.
  • 42
    • 0011299687 scopus 로고    scopus 로고
    • note
    • Separate samples were exposed to 0.3 M KOH in 33% acetonitrile for different periods of time. Each sample was immersed into the 0.3 M KOH in 33% acetonitrile for a given period of time at room temperature (∼25 °C), withdrawn from the solution, rinsed with water and acetonitrile, blown dry with nitrogen, and then characterized by IRS or XPS.
  • 43
    • 0011343572 scopus 로고    scopus 로고
    • note
    • Each of the mNBT monolayer samples was immersed into the 0.50 M n-butylamine in acetonitrile for a given period of time at room temperature (∼25 °C), withdrawn from the solution, rinsed with acetonitrile, blown dry with nitrogen, and then characterized by IRS or XPS. This process was repeated with the same sample until most of the ester was aminolyzed.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.