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The expression "eclipsed" has been used in the literature to describe conformers of oligosilane with dihedral angle of 0" and 120". We suggest that the former conformer be called "syn", and that "eclipsed" be used exclusively to define a conformer with a dihedral angle of 120°. See: JhalaliHeravi, M.; McManus, S. P.; Zutaut, S. E.; McDonald, J. K. Chem. Mater. 1991, 3, 1024.
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more..
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20
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33751429986
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note
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In the related hexasilane, a methyl group on each of Si(l) and Si(4) of 1 is replaced by a dimethylphenylsilyl group. The Si2-Si3-Si4-Si5 dihedral angle about its central Si-Si bond is 117.5° as determined by single-crystal X-ray crystallography.12
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