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Volumn 105, Issue 45, 2001, Pages 10246-10248

UV, MCD, and LD spectra of a conformationally constrained orrôo-tetrasilane: Support for the avoided crossing model of conformational effects on excited states

Author keywords

[No Author keywords available]

Indexed keywords

EXCITED STATES;

EID: 0035892195     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp010792z     Document Type: Article
Times cited : (25)

References (34)
  • 5
    • 0031998022 scopus 로고    scopus 로고
    • and references therein
    • Yuan, C.-H.; West, R. Macromolecules 1998, 31, 1087 and references therein.
    • (1998) Macromolecules , vol.31 , pp. 1087
    • Yuan, C.-H.1    West, R.2
  • 13
    • 0034519392 scopus 로고    scopus 로고
    • A recently proposed set of labels is adopted to describe linear chain conformers: Michl, J.; West, R. Ace. Chem. Res. 2000, 33, 821.
    • (2000) Ace. Chem. Res. , vol.33 , pp. 821
    • Michl, J.1    West, R.2
  • 16
    • 0000062047 scopus 로고
    • The expression "eclipsed" has been used in the literature to describe conformers of oligosilane with dihedral angle of 0" and 120". We suggest that the former conformer be called "syn", and that "eclipsed" be used exclusively to define a conformer with a dihedral angle of 120°. See: JhalaliHeravi, M.; McManus, S. P.; Zutaut, S. E.; McDonald, J. K. Chem. Mater. 1991, 3, 1024.
    • (1991) Chem. Mater. , vol.3 , pp. 1024
    • Jhalaliheravi, M.1    McManus, S.P.2    Zutaut, S.E.3    McDonald, J.K.4
  • 20
    • 33751429986 scopus 로고    scopus 로고
    • note
    • In the related hexasilane, a methyl group on each of Si(l) and Si(4) of 1 is replaced by a dimethylphenylsilyl group. The Si2-Si3-Si4-Si5 dihedral angle about its central Si-Si bond is 117.5° as determined by single-crystal X-ray crystallography.12


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