Ammonia synthesis over a multipromoted iron catalyst: Extended set of activity measurements, microkinetic model, and hydrogen inhibition

Journal of Catalysis

Volumn 188, Issue 1, 1999, Pages 83-89

  Sehested, Jens ^a   Jacobsen, Claus J H ^a   Törnqvist, Eric ^a   Rokni, Said ^a   Stoltze, Per ^b  

^a HALDOR TOPSØE A S   (Denmark)

^b TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

Author keywords

Ammonia synthesis; Microkinetic analysis; Multipromoted iron catalyst

Indexed keywords

EID: 0035891438     PISSN: 00219517     EISSN: None     Source Type: Journal    
DOI: 10.1006/jcat.1999.2628     Document Type: Article

References (23)

1. Temkin, M. I., Morozov, N. M., and Shapatina, E. N., Kinet. I Kataliz. 4, 260 (1963).
2. Nielsen, A., "An Investigation on Promoted Iron Catalysts for the Synthesis of Ammonia," 3rd ed., Gjellerup, 1968.
3. Kowalczyk, Z., Catal. Lett. 37, 403 (1996).
4. Kowalczyk, Z., Sentek, J., Jodzis, S., Muhler, M., and Hinrichsen, O., J. Catal. 169, 407 (1997).
5. Stoltze, P., Phys. Scripta. 36, 824 (1987).
6. Stoltze, P., and Nørskov, J. K., Phys. Rev Lett. 55, 2502 (1985).
7. Stoltze, P., and Nørskov, J. K., Surf. Sci. Lett. 197, L230 (1988).
8. Stoltze, P., and Nørskov, J. K., J. Catal. 110, 1 (1988).
9. Stoltze, P., and Nørskov, J. K., Topics in Catal. 1, 253 (1994).
10. Bowker, M., Parker, I. B., and Waugh, K. C., Appl. Catal. 14, 101 (1985).
11. Parker, I. B., Waugh, K. C., and Bowker, M., J. Catal. 114, 457 (1988).
12. Bowker, M., Parker, I. B., and Waugh, K. C., Surf. Sci. 197, L223 (1988).
13. Bowker, M., Catal. Today 12, 153 (1992).
14. Fastrup, B., Topics in Catal. 1, 273 (1994).
15. Dumesic, J. A., and Trevino, A. A., J. Catal. 116, 119 (1989).
16. Aparicio, L. M., and Dumesic, J. A., Topics in Catal. 1, 233 (1994).
17. Fastrup, B., and Nielsen, H. N., Catal. Lett. 14, 233 (1992).
18. Rosowski, F., and Muhler, M., in "Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis," p. 111. Elsevier, Amsterdam, 1997.
19. Højlund Nielsen, P. E., in "Ammonia, Catalyst and Manufacture" (A. Nielsen, Ed.), p. 191, Springer-Verlag, Berlin/New York, 1995.
20. Ertl, G., Lee, S. B., and Weiss, M., Surf. Sci. 114, 527 (1982).
21. Fastrup, B., J. Catal. 150, 345 (1994).
22. Nielsen, A., Catal. Rev. Sci. Eng. 23, 17 (1981).
23. Ertl., G., Lee, S. B., and Weiss, M., Surf. Sci. 111, L711 (1981).