Correlation between local mobility and mechanical properties of high-speed melt-spun nylon-6 fibers

Journal of Polymer Science, Part B: Polymer Physics

Volumn 39, Issue 10, 2001, Pages 993-1000

  Kwak, Seung Yeop ^a,b   Kim, Jun Hyung ^b   Lee, Jonc Chan ^a,b  

^a Hyperstructured Organic Materials Research Center   (South Korea)

^b Seoul National University   (South Korea)

Author keywords

Correlation time ( c); High speed melt spun nylon 6 fiber; Local molecular mobility; Solid state pulsed wide line 1H NMR spectroscopy; Spin lattice relaxation time in the rotating frame (T1 ); Tensile property; Thermal stress

Indexed keywords

AMORPHOUS MATERIALS; CRYSTALLINE MATERIALS; ELASTIC MODULI; MELT SPINNING; MOLECULAR DYNAMICS; MOLECULAR ORIENTATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; NYLON TEXTILES; PHASE TRANSITIONS; TENACITY; TENSILE STRENGTH; THERMAL STRESS;

AMORPHOUS CHAINS; ELONGATION AT BREAK; MOLECULAR MOBILITY; NYLON FIBER; RIGID AMORPHOUS PHASE; SPIN-LATTICE RELAXATION TIME;

SYNTHETIC FIBERS;

EID: 0035873411     PISSN: 08876266     EISSN: None     Source Type: Journal    
DOI: 10.1002/polb.1076     Document Type: Article

References (18)

1. Ziabicki, A. Fundamentals of Fiber Formation; Wiley: London, 1976; pp 1-11.
2. Stepaniak, R. F.; Carton, A.; Carlsson, D. J.; Wiles, D. M. J Appl Polym Sci 1979, 23, 1747.
3. Stepaniak, R. F.; Carton, A.; Carlsson, D. J.; Wiles, D. M. J Polym Sci Polym Phys Ed 1979, 17, 987.
4. Heuvel, H. M.; Huisman, R. J Appl Polym Sci 1981, 26, 713.
5. Gianchandani, J.; Spruiell, J. E.; Clark, E. S. J Appl Polym Sci 1982, 27, 3527.
6. Salem, D. R.; Moore, R. A. F.; Weigmann, H. D. J Polym Sci Part B: Polym Phys 1987, 25, 567.
7. Murase, S.; Kashima, M.; Kudo, K.; Hirami, M. Macromol Chem Phys 1997, 198, 561.
8. Murthy, N. S.; Bray, R. G.; Correals, S. T.; Moore, R. A. F. Polymer 1995, 36, 3863.
9. Murthy, N. S.; Minor, H.; Bednarczyk, C. Macromolecules 1993, 26, 1712.
10. Kwak, S.-Y.; Kim, J. H.; Kim, S. Y.; Jeong, H. G.; Kwon, I. H. J Polym Sci Part B: Polym Phys 2000, 38, 1285.
11. Gentzler, M.; Reimer, J. H. Macromolecules 1997, 30, 8365.
12. Mcbriety, V. J.; Packer, K. J. Nuclear Magnetic Resonance in Solid Polymers; Cambridge University Press: New York, 1993; pp 29-44.
13. Bloembergen, N.; Purcell, E. M.; Pound, R. V. Phys Rev 1948, 73, 679.
14. Jones, G. P. Phys Rev 1966, 148, 332.
15. Harris, R. K. Nuclear Magnetic Resonance Spectroscopy; Pitman: London, 1983; pp 66-95.
16. Kubo, R.; Tomita, K. J Phys Soc Jpn 1954, 9, 888.
17. Wauch, J. S. Advances in Magnetic Resonance; Academic: New York, 1968; pp 43-78.
18. Suzuki, A.; Koito, K. J Polym Sci Part B: Polym Phys 2000, 38, 1137.