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Under our experimental conditions, some DBP is ionized by the pump pulse alone through the absorption of at least three photons, and this gives a background signal for the parent and fragment masses at negative delay times. At positive delay times, the background ion signal at 202 amu is constantly decreased while that at 41 amu is constantly increased, due to parent ion fragmentation by the probe pulse. This explains why we always obtain a negative signal offset in the parent transient (202 amu) and a positive offset in the fragment transient (41 amu). We had to maintain a relatively strong pump energy in order to clearly see the modulation with large S/N.
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