A Stereoselective synthesis of the C10-C31 (BCDEF ring) portion of pinnatoxin A

Organic Letters

Volumn 3, Issue 25, 2001, Pages 4075-4078

  Nakamura, Seiichi ^a   Inagaki, Jun ^a   Sugimoto, Tomohiro ^a   Kudo, Masashi ^a   Nakajima, Makoto ^a   Hashimoto, Shunichi ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKALOID; MARINE TOXIN; PINNATOXIN A; SPIRO COMPOUND;

ANIMAL; ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; MOLLUSC; STEREOISOMERISM; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ALKALOIDS; ANIMAL; CRYSTALLOGRAPHY, X-RAY; MARINE TOXINS; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; MOLLUSCA; SPIRO COMPOUNDS; STEREOISOMERISM; SUPPORT, NON-U.S. GOV'T;

EID: 0035856898     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol0168364     Document Type: Article

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33. 2O (4:1), 93%.
34. -1 indicated the existence of a nonconjugated ketone carbonyl.
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39. The ratios of 18, 19, 20, and another unidentified isomer after 4 and 48 h were 85:8:3:4 and 82:8:6:4, respectively.
40. 4c However, they did not mention the result of epimerization of the desired isomer.
41. 2O, -78 °C, 73%.