메뉴 건너뛰기




Volumn 17, Issue 23, 2001, Pages 7198-7203

Selectivity in the oxidation of limonene by amphiphilized metalloporphyrins in micellar media

Author keywords

[No Author keywords available]

Indexed keywords

EPOXIDATION;

EID: 0035856644     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la010082k     Document Type: Article
Times cited : (25)

References (44)
  • 28
    • 0011280315 scopus 로고    scopus 로고
    • 1H NMR experiments were carried out on the assumption that only micelle-solubilized limonene contributes to the limonene NMR Signals. This is a reasonable assumption because of the insolubility of limonene in water; moreover, we observed that unbound limonene floats on the surface of micelle solution.
    • 1H NMR experiments were carried out on the assumption that only micelle-solubilized limonene contributes to the limonene NMR Signals. This is a reasonable assumption because of the insolubility of limonene in water; moreover, we observed that unbound limonene floats on the surface of micelle solution.
  • 30
    • 33845554951 scopus 로고
    • These media mimic the polarity of the aqueous interface of CTAB and Brij, respectively; for references see: (a) Ramachandran, C.; Pyter, R.A.; Mukerjee, O. J. Phys. Chem. 1982, 86, 3198.
    • (1982) J. Phys. Chem. , vol.86 , pp. 3198
    • Ramachandran, C.1    Pyter, R.A.2    Mukerjee, O.3
  • 31
    • 0000015416 scopus 로고
    • Mittal, K.L., Lindman, B., Eds.; Plenum Press: New York
    • (b) Romsted, L.S. In Surfactants in Solution; Mittal, K.L., Lindman, B., Eds.; Plenum Press: New York, 1984; Vol. 2, p 1015.
    • (1984) Surfactants in Solution , vol.2 , pp. 1015
    • Romsted, L.S.1
  • 32
    • 0011284862 scopus 로고    scopus 로고
    • -3 M.
    • -3 M.
  • 33
    • 0011329810 scopus 로고    scopus 로고
    • Better conditions for the epoxidation in SDS have not been investigated because we used it only as an anionic surfactant reference.
    • Better conditions for the epoxidation in SDS have not been investigated because we used it only as an anionic surfactant reference.
  • 34
    • 0015527085 scopus 로고
    • It is well-known, in fact, that the formation of dimers or higher aggregates causes an evident broadening of the porphyrin absorption bands. For studies on the aggregation of water soluble porphyrins in aqueous solution, see ref 2e and the following: (a) Pasternack, R.F.; Huber, P.R.; Boyd, P.; Engasser, G.; Francesconi, L.; Gibbs, E.; Fasella, P.; Cerio Venturo, G.; deC. Hinds, L. J. Am. Chem. Soc. 1972, 94, 4511. (b) Guilard, R.; Senglet, N.; Liu, Y.H.; Sazou, D.; Findsen, E.; Faure, D.; Des Courierer, T.; Kadish, K.M. Inorg. Chem. 1991, 30, 1898. (c) Kano, K.; Minamizono, H.; Kitae, T.; Negi, S. J. Phys. Chem. 1997, 101, 6118. For related studies in vesicle bilayers. See (d) Van Esch, J.H.; Feiters, M.C.; Peters, A.M.; Nolte, R.J.M. J. Phys. Chem. 1994, 98, 5541.
    • (1972) J. Am. Chem. Soc. , vol.94 , pp. 4511
    • Pasternack, R.F.1    Huber, P.R.2    Boyd, P.3    Engasser, G.4    Francesconi, L.5    Gibbs, E.6    Fasella, P.7    Cerio Venturo, G.8    Hinds, L.DeC.9
  • 35
    • 0001355389 scopus 로고
    • It is well-known, in fact, that the formation of dimers or higher aggregates causes an evident broadening of the porphyrin absorption bands. For studies on the aggregation of water soluble porphyrins in aqueous solution, see ref 2e and the following: (a) Pasternack, R.F.; Huber, P.R.; Boyd, P.; Engasser, G.; Francesconi, L.; Gibbs, E.; Fasella, P.; Cerio Venturo, G.; de C. Hinds, L. J. Am. Chem. Soc. 1972, 94, 4511. (b) Guilard, R.; Senglet, N.; Liu, Y.H.; Sazou, D.; Findsen, E.; Faure, D.; Des Courierer, T.; Kadish, K.M. Inorg. Chem. 1991, 30, 1898. (c) Kano, K.; Minamizono, H.; Kitae, T.; Negi, S. J. Phys. Chem. 1997, 101, 6118. For related studies in vesicle bilayers. See (d) Van Esch, J.H.; Feiters, M.C.; Peters, A.M.; Nolte, R.J.M. J. Phys. Chem. 1994, 98, 5541.
    • (1991) Inorg. Chem. , vol.30 , pp. 1898
    • Guilard, R.1    Senglet, N.2    Liu, Y.H.3    Sazou, D.4    Findsen, E.5    Faure, D.6    Des Courierer, T.7    Kadish, K.M.8
  • 36
    • 0031210116 scopus 로고    scopus 로고
    • It is well-known, in fact, that the formation of dimers or higher aggregates causes an evident broadening of the porphyrin absorption bands. For studies on the aggregation of water soluble porphyrins in aqueous solution, see ref 2e and the following: (a) Pasternack, R.F.; Huber, P.R.; Boyd, P.; Engasser, G.; Francesconi, L.; Gibbs, E.; Fasella, P.; Cerio Venturo, G.; de C. Hinds, L. J. Am. Chem. Soc. 1972, 94, 4511. (b) Guilard, R.; Senglet, N.; Liu, Y.H.; Sazou, D.; Findsen, E.; Faure, D.; Des Courierer, T.; Kadish, K.M. Inorg. Chem. 1991, 30, 1898. (c) Kano, K.; Minamizono, H.; Kitae, T.; Negi, S. J. Phys. Chem. 1997, 101, 6118. For related studies in vesicle bilayers. See (d) Van Esch, J.H.; Feiters, M.C.; Peters, A.M.; Nolte, R.J.M. J. Phys. Chem. 1994, 98, 5541.
    • (1997) J. Phys. Chem. , vol.101 , pp. 6118
    • Kano, K.1    Minamizono, H.2    Kitae, T.3    Negi, S.4
  • 37
    • 33750898216 scopus 로고
    • It is well-known, in fact, that the formation of dimers or higher aggregates causes an evident broadening of the porphyrin absorption bands. For studies on the aggregation of water soluble porphyrins in aqueous solution, see ref 2e and the following: (a) Pasternack, R.F.; Huber, P.R.; Boyd, P.; Engasser, G.; Francesconi, L.; Gibbs, E.; Fasella, P.; Cerio Venturo, G.; de C. Hinds, L. J. Am. Chem. Soc. 1972, 94, 4511. (b) Guilard, R.; Senglet, N.; Liu, Y.H.; Sazou, D.; Findsen, E.; Faure, D.; Des Courierer, T.; Kadish, K.M. Inorg. Chem. 1991, 30, 1898. (c) Kano, K.; Minamizono, H.; Kitae, T.; Negi, S. J. Phys. Chem. 1997, 101, 6118. For related studies in vesicle bilayers. See (d) Van Esch, J.H.; Feiters, M.C.; Peters, A.M.; Nolte, R.J.M. J. Phys. Chem. 1994, 98, 5541.
    • (1994) J. Phys. Chem. , vol.98 , pp. 5541
    • Van Esch, J.H.1    Feiters, M.C.2    Peters, A.M.3    Nolte, R.J.M.4
  • 38
    • 0024716284 scopus 로고
    • The hydrophobicity of a given substrate may be quantified by "logP" values, where P is the partition constants of the substrate between n-octanol and water. Cyclohexene log P = 2.12; cyclooctene log P = 2.91, limonene log P = 2.94. Calculation of log P is carried out according to: Viswanadan, V.N.; Ghose, A.K.; Revankar, G.N.; Robins, R.K. J. Chem. Inf. Comput. Sci. 1989, 29, 163.
    • (1989) J. Chem. Inf. Comput. Sci. , vol.29 , pp. 163
    • Viswanadan, V.N.1    Ghose, A.K.2    Revankar, G.N.3    Robins, R.K.4
  • 41
    • 0002048408 scopus 로고    scopus 로고
    • Kadish, K.M., Smith, K.M., Guilard, R., Eds.; Academic Press: London
    • (c) Suslick, K.S. In The porphyrin Handbook; Kadish, K.M., Smith, K.M., Guilard, R., Eds.; Academic Press: London, 2000; Vol. 4, p 41.
    • (2000) The porphyrin Handbook , vol.4 , pp. 41
    • Suslick, K.S.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.