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1H NMR experiments were carried out on the assumption that only micelle-solubilized limonene contributes to the limonene NMR Signals. This is a reasonable assumption because of the insolubility of limonene in water; moreover, we observed that unbound limonene floats on the surface of micelle solution.
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1H NMR experiments were carried out on the assumption that only micelle-solubilized limonene contributes to the limonene NMR Signals. This is a reasonable assumption because of the insolubility of limonene in water; moreover, we observed that unbound limonene floats on the surface of micelle solution.
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Better conditions for the epoxidation in SDS have not been investigated because we used it only as an anionic surfactant reference.
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Better conditions for the epoxidation in SDS have not been investigated because we used it only as an anionic surfactant reference.
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It is well-known, in fact, that the formation of dimers or higher aggregates causes an evident broadening of the porphyrin absorption bands. For studies on the aggregation of water soluble porphyrins in aqueous solution, see ref 2e and the following: (a) Pasternack, R.F.; Huber, P.R.; Boyd, P.; Engasser, G.; Francesconi, L.; Gibbs, E.; Fasella, P.; Cerio Venturo, G.; deC. Hinds, L. J. Am. Chem. Soc. 1972, 94, 4511. (b) Guilard, R.; Senglet, N.; Liu, Y.H.; Sazou, D.; Findsen, E.; Faure, D.; Des Courierer, T.; Kadish, K.M. Inorg. Chem. 1991, 30, 1898. (c) Kano, K.; Minamizono, H.; Kitae, T.; Negi, S. J. Phys. Chem. 1997, 101, 6118. For related studies in vesicle bilayers. See (d) Van Esch, J.H.; Feiters, M.C.; Peters, A.M.; Nolte, R.J.M. J. Phys. Chem. 1994, 98, 5541.
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It is well-known, in fact, that the formation of dimers or higher aggregates causes an evident broadening of the porphyrin absorption bands. For studies on the aggregation of water soluble porphyrins in aqueous solution, see ref 2e and the following: (a) Pasternack, R.F.; Huber, P.R.; Boyd, P.; Engasser, G.; Francesconi, L.; Gibbs, E.; Fasella, P.; Cerio Venturo, G.; de C. Hinds, L. J. Am. Chem. Soc. 1972, 94, 4511. (b) Guilard, R.; Senglet, N.; Liu, Y.H.; Sazou, D.; Findsen, E.; Faure, D.; Des Courierer, T.; Kadish, K.M. Inorg. Chem. 1991, 30, 1898. (c) Kano, K.; Minamizono, H.; Kitae, T.; Negi, S. J. Phys. Chem. 1997, 101, 6118. For related studies in vesicle bilayers. See (d) Van Esch, J.H.; Feiters, M.C.; Peters, A.M.; Nolte, R.J.M. J. Phys. Chem. 1994, 98, 5541.
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It is well-known, in fact, that the formation of dimers or higher aggregates causes an evident broadening of the porphyrin absorption bands. For studies on the aggregation of water soluble porphyrins in aqueous solution, see ref 2e and the following: (a) Pasternack, R.F.; Huber, P.R.; Boyd, P.; Engasser, G.; Francesconi, L.; Gibbs, E.; Fasella, P.; Cerio Venturo, G.; de C. Hinds, L. J. Am. Chem. Soc. 1972, 94, 4511. (b) Guilard, R.; Senglet, N.; Liu, Y.H.; Sazou, D.; Findsen, E.; Faure, D.; Des Courierer, T.; Kadish, K.M. Inorg. Chem. 1991, 30, 1898. (c) Kano, K.; Minamizono, H.; Kitae, T.; Negi, S. J. Phys. Chem. 1997, 101, 6118. For related studies in vesicle bilayers. See (d) Van Esch, J.H.; Feiters, M.C.; Peters, A.M.; Nolte, R.J.M. J. Phys. Chem. 1994, 98, 5541.
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The hydrophobicity of a given substrate may be quantified by "logP" values, where P is the partition constants of the substrate between n-octanol and water. Cyclohexene log P = 2.12; cyclooctene log P = 2.91, limonene log P = 2.94. Calculation of log P is carried out according to: Viswanadan, V.N.; Ghose, A.K.; Revankar, G.N.; Robins, R.K. J. Chem. Inf. Comput. Sci. 1989, 29, 163.
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