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Iodine ate complexes as 10-X-2 species have been postulated as intermediates in iodine-metal exchange reactions, evidence regarding their formation has been accrued, and calculations supporting their stability have been reported.
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-, has recently been calculated to enjoy substantial stabilization; cf. also the observations reported in ref 11.
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28
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0011518134
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note
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Such a behavior has been noted with various (1-iodo-2-phenylethyl)magnesium species.
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-
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29
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0347177651
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and references quoted therein.
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30
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0011416592
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note
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2CHMgX (3, +12 ppm).
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