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Volumn 105, Issue 18, 2001, Pages 4574-4578

Effect of pressure on the intersystem crossing between the encounter complex pairs involved in triplet-triplet annihilation of 2-acetonaphthone in liquid solution

Author keywords

[No Author keywords available]

Indexed keywords

INTERSYSTEM CROSSING;

EID: 0035837033     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp004172u     Document Type: Article
Times cited : (12)

References (37)
  • 21
    • 85037301483 scopus 로고    scopus 로고
    • (21) Tanaka, F. Private communication.
    • , vol.21
  • 23
    • 85037324706 scopus 로고    scopus 로고
    • (23) Okamoto, M. Unpublished results.
    • , vol.23
  • 31
    • 85037319855 scopus 로고    scopus 로고
    • note
    • The radial distribution function at the closest approach distance, 2rnt with the hard sphere assumption, g(rmM) is given by30 g(rMM ) = [1/(1 - >)] + {[3>-/(l - >02](rrciI/-s)} + [2rV(l - >03(rred/rs)2] (Al), where rs is the radius of solvent and rrea = nn'/2, and y is the packing fraction, given in terms of the molar volume of solvent, Vs, by y = 4Nrs/3Vs (A2). By using the values of rs and rn listed in Table 2, together with the data of the solvent density,25"28 gfofM) was calculated by (Al).
  • 33
    • 85037315148 scopus 로고    scopus 로고
    • note
    • The value of asw is calculated by asw = 3000/M. (A3), where/M. is a microfriction factor, given by/\i-sw = (0.16 + 0.4rM./rs)(0.9 + 0.47V - 0.25rM.0 (A4). In eq A4, Tsr and TM-' are the reduced temperatures of solvent and solute, respectively, which can be calculated by the method described elsewhere.3-12'13 The values of/M.sw(full) and/M.sw(trunc) were evaluated by eq A4 and by neglecting the second parenthetical quantity in eq A4, respectively.3
  • 36
    • 85037325946 scopus 로고    scopus 로고
    • The values of van der Waals radius were evaluated to be 0.268 and 0.345 nm for benzene and benzophenone, respectively, by the method of Bondi.32
    • The values of van der Waals radius were evaluated to be 0.268 and 0.345 nm for benzene and benzophenone, respectively, by the method of Bondi.32


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.