Kinetic modelling of the transformation of aqueous ethanol into hydrocarbons on a HZSM-5 zeolite

Industrial and Engineering Chemistry Research

Volumn 40, Issue 16, 2001, Pages 3467-3474

  Gayubo, A G ^a   Tarrio A M ^a   Aguayo, A T ^a   Olazar, M ^a   Bilbao, J ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ATTENUATION; FERMENTATION; HYDROCARBONS; ZEOLITES;

KINETIC MODELLING;

ETHANOL;

ALCOHOL; CARBOHYDRATE; ETHER; ETHYLENE; HYDROCARBON; METHANOL; WATER; ZEOLITE;

ETHANOL; HYDROCARBON; KINETICS; TRANSFORMATION (METALLURGY); ZEOLITE;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CHEMICAL COMPOSITION; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; FERMENTATION; HIGH TEMPERATURE; MODEL; REACTION ANALYSIS; REACTOR;

EID: 0035827848     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie001115e     Document Type: Article

References (48)

1. Recovery of ethanol from fermentation broths by catalytic conversion to gasoline
2. Recovery of ethanol from fermentation broths by catalytic conversion to gasoline. 2. Energy analysis
3. The conversion of dimethyl ether to hydrocarbons on zeolite H-ZSM-5. The reaction mechanism for formation of primary olefins
4. The reaction mechanism of the first C-C bond formation in the methanol to gasoline process
5. Acidic properties of ZSM-5 zeolite and conversion of ethanol to diethyl ether
6. Mechanism of hydrocarbon formation from methanol
7. Kinetics of methanol dehydration on dealuminated H-mordenite: Model with acid and basic active centres
8. Interaction of methanol with bronsted acid sites of zeolite catalysts: An ab initio study
9. Methanol adsorption in zeolites - A first-principles study
10. Ethanol to gasoline process: Effect of variables, mechanism, and kinetics
11. Conversion of ethanol over zeolite H-ZSM-5
12. MTG revisited
13. On the mechanism of hydrocarbon formation from methanol over protonated zeolites
14. On the reaction mechanism for propene formation in the MTO reaction over SAPO-34
15. Methanol conversion to hydrocarbons. Use of isotopes for mechanism studies
16. A reactor design simulation with reversible and irreversible catalyst deactivation
17. Development of Mobil's fixed-bed methanol-to-gasoline (MTG) process
18. MTG process in a fluidized bed with catalyst circulation: Operation and simulation of an experimental unit
19. Simulation of the MTG process and operation of an experimental unit of fluidized bed reactor-regenerator with catalyst circulation
20. Kinetic modelling of methanol transformation into olefins on a SAPO-34 catalyst
21. Evidence of autocatalysis in methanol to hydrocarbons reactions over zeolite catalysts
22. A kinetic model for methanol conversion to hydrocarbons
23. Modelling methanol conversion to hydrocarbons: Alternative kinetic models
24. Modelling methanol conversion to hydrocarbons: Revision and testing of a simple kinetic model
25. Concentration-dependent kinetic model for catalyst deactivation in the MTG process
26. Analysis of kinetic models of the MTG Process in an integral reactor
27. Catalyst deactivation by coke in the MTG process in fixed and fluidized beds reactors
28. Conversion of ethanol over zeolite HZSM-5 in the presence of water
29. Ethylene from ethanol over zeolite catalysts
30. The bioethanol-to-ethylene (BETE) process
31. HZSM-5 catalysed conversion of aqueous ethanol to hydrocarbons
32. Production of ethylene from hydrous ethanol on H-ZSM-5 under mild conditions
33. Conversion of ethanol in aqueous solution over ZSM-5 zeolites. Influence of reaction parameters and catalyst acidic properties as studied by ammonia TPD technique
34. Conversion of ethanol in aqueous solution over ZSM-5 Zeolites. Study of the reaction network
35. Catalyst equilibration for transformation of methanol into hydrocarbons by reaction-regeneration cycles
36. A new method of constrained optimization and a comparison with other methods
37. Estimation of parameters for nonlinear least squares analysis
38. Sequential experimental design for precise parameter estimation. 1. Use of reparametrization
39. An algorithm for least-squares estimation of nonlinear parameters
40. Methanol conversion to Olefins over ZSM-5. II. Olefin distribution
41. Conversion of methanol to hydrocarbons. II. Reaction paths for Olefin formation over HZSM-5 zeolite catalyst
42. Coking, aging and regeneration of zeolites. XIV. Kinetic study of the formation of coke from propene over USHY and H-ZSM-5
43. Catalytic conversion of methanol to light alkenes on SAPO molecular Sieves