Asymmetric syntheses of fused bicyclic compounds by conjugate additions of allylic organolithium species to activated olefins and subsequent cyclizations

Organic Letters

Volumn 3, Issue 5, 2001, Pages 711-713

  Lim, Sung H ^a   Curtis, Michael D ^a,b   Beak, Peter ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

^b PROCTER AND GAMBLE PHARMACEUTICALS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; BICYCLO COMPOUND; LIGAND; LITHIUM DERIVATIVE;

ARTICLE; CHEMISTRY; CYCLIZATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOISOMERISM; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ALKENES; BICYCLO COMPOUNDS; CRYSTALLOGRAPHY, X-RAY; CYCLIZATION; LIGANDS; LITHIUM COMPOUNDS; MAGNETIC RESONANCE SPECTROSCOPY; STEREOISOMERISM;

EID: 0035826342     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol007012+     Document Type: Article

References (18)

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11. 3.
12. 6b
13. The absolute configuration of 9 was assigned by derivatization and X-ray crystallography using anomalous dispersion. The determination of the absolute configuration is detailed in Supporting Information.
14. The crystallographic data for derivative of 9, 16, and 37 have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. 154907, 154565, and 154566, respectively. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, U.K. (fax: (+44)1223-336033; email: deposit@ ccdc.cam.ac.uk).
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