Combining solvent engineering and thermodynamic modeling to enhance selectivity during monoglyceride synthesis by lipase-catalyzed esterification

Enzyme and Microbial Technology

Volumn 28, Issue 4-5, 2001, Pages 362-369

  Bellot, Jean Christophe ^a   Choisnard, Luc ^a   Castillo, Edmundo ^a   Marty, Alain ^a  

^a UMR792 INGÉNIERIE DES SYSTÈMES BIOLOGIQUES ET DES PROCÉDÉS   (France)

Author keywords

Esterification; Lipase; Monoglyceride; Thermodynamic modeling; UNIFAC

Indexed keywords

2 METHYL 2 BUTANOL; BUTANOL; GLYCEROL; HEXANE; MONOACYLGLYCEROL; OLEIC ACID; ORGANIC SOLVENT; SILICA GEL; TRIACYLGLYCEROL LIPASE; UNCLASSIFIED DRUG; WATER;

ARTICLE; CATALYST; CONTROLLED STUDY; CORRELATION FUNCTION; ENZYME IMMOBILIZATION; ENZYME SUBSTRATE COMPLEX; ENZYME SYNTHESIS; ESTERIFICATION; NONHUMAN; PARTITION COEFFICIENT; RHIZOMUCOR; THERMODYNAMICS; VALIDATION PROCESS;

EID: 0035826291     PISSN: 01410229     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0141-0229(00)00326-4     Document Type: Article

References (9)

1. Enzymatic esterification of glycerol II. Lipase-catalyzed synthesis of regioisomerically pure 1(3)-rac-monoacylglycerols
2. The role of silica gel in lipase-catalyzed esterification reactions of high polar substrates
3. Efficient lipase-catalyzed production of tailor-made emulsifiers using solvent engineering coupled to extractive processing
4. Kinetic study of the lipase-catalyzed synthesis of triolein
5. Prediction of water adsorption curves for heterogeneous biocatalysis in organic and supercritical solvents
6. Group-contribution estimation of activity coefficients in nonideal liquid mixtures
7. From UNIFAC to modified UNIFAC to PSRK with the help of DDB
8. Solvent selection for biocatalysis in mainly organic systems: Predictions of effects on equilibrium position