The first structurally authenticated Rb-PR3 and Cs-PR3 contacts. Synthesis and crystal structures of [Rb{(Me3Si)2CP(C6H4-2-CH2 NMe2)2}]n and [Cs{(Me3Si)2CP(C6H4-2-CH2 NMe2)2}(toluene)]n

Organometallics

Volumn 20, Issue 3, 2001, Pages 367-369

  Izod, Keith ^a   Clegg, William ^a   Liddle, Stephen T ^a  

^a NEWCASTLE UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ETHYLHEXYL; PHOSPHINOMETHANIDE LIGAND;

BINDING ENERGY; CESIUM COMPOUNDS; CHEMICAL BONDS; COMPLEXATION; CRYSTAL STRUCTURE; CRYSTALLIZATION; POSITIVE IONS; SYNTHESIS (CHEMICAL); TOLUENE;

RUBIDIUM COMPOUNDS;

EID: 0035809268     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0008732     Document Type: Article

References (24)

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2. Pearson, R. G. Chemical Hardness; Wiley-VCH: Weinheim, 1997.
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6. (b) Rabe, G. W.; Heise, H.; Yap, G. P. A.; Liable-Sands, L. M.; Rheingold, A. L. Inorg. Chem. 1998, 37, 4235.
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13. (a) Clegg, W.; Doherty, S.; Izod, K.; O'Shaughnessy, P. Chem. Commun. 1998, 1129.
14. (b) Clegg, W.; Izod, K.; O'Shaughnessy, P. Organometallics 1999, 18, 2939.
15. (c) Hill, M. N. S.; Izod, K.; O'Shaughnessy, P.; Clegg, W. Organometallics 2000, 19, 4531.
16. Karsch, H. H.; Zellner, K.; Gamper, S.; Müller, G. J. Organomet. Chem. 1991, 414, C39.
17. 8, 300 K): δ 1.97.
18. -3.
19. -3.
20. (a) Schade, C.; Schleyer, P. v R. Adv. Organomet. Chem. 1987, 27, 169.
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24. 3 (M = Rb or Cs) were prepared by the direct reaction of 2-ethylhexanol with the respective alkali metal in diethyl ether. Removal of solvent gave the alkali metal alkoxides as colorless solids in quantitative yields.