Dodeca(benzyloxy)dodecaborane, B12(OCH2Ph)12: A stable derivative of hypercloso-B12H12

Angewandte Chemie - International Edition

Volumn 40, Issue 9, 2001, Pages 1664-1667

  Peymann, Toralf ^a   Knobler, Carolyn B ^a   Khan, Saeed I ^a   Hawthorne, M Frederick ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Boranes; Boron; Closomers; Cluster compounds; Electron deficient compounds

Indexed keywords

CHLORINE COMPOUNDS; IRON COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION;

ELECTRONIC SPECTROSCOPY;

AROMATIC HYDROCARBONS;

BENZYL CHLORIDE; BORANE DERIVATIVE; BORON; FERROUS ION;

ALKYLATION; ARTICLE; CRYSTAL STRUCTURE; CYCLIC POTENTIOMETRY; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0035805304     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20010504)40:9<1664::AID-ANIE16640>3.0.CO;2-O     Document Type: Article

References (19)

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10. 12 cluster retains 26 skeletal electrons and thus two negative charges are delocalized throughout the icosahedral cluster.
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16. 6). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+ 44)1223-336-033; e-mail: deposit@ccdc.cam. ac.uk).
17. 1. The structure was solved by statistical methods. R 0.073. wR = 0.186.
18. 1. The structure was solved by statistical methods. R = 0.048, wR = 0.118.
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