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Volumn 637-639, Issue , 2001, Pages 507-513

Ferrocene substituted nitronyl nitroxide and imino nitroxide radicals. Synthesis, X-ray structure and magnetic properties

Author keywords

Crystal structures; Ferrocene; Magnetochemistry; Organic radical

Indexed keywords


EID: 0035803779     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(01)00954-8     Document Type: Article
Times cited : (18)

References (13)
  • 6
    • 0033531611 scopus 로고    scopus 로고
    • In order to overcome such inconveniences, diradical 1 consisting of two polychlorinated triphenylmethyl radicals connected by a 1,1′-ferrocenylendivinylene bridge, was synthesized. The particular structure and topology of such a diradical allow a non-negligible spin density on the ferrocene moiety making feasible the magnetic coupling between the two organic radical units. In addition, the location of both radical units far away from each other avoids any possibility of having intramolecular hydrogen bond interactions, and consequently, a significant direct through-space magnetic interaction:
    • In order to overcome such inconveniences, diradical 1 consisting of two polychlorinated triphenylmethyl radicals connected by a 1,1′-ferrocenylendivinylene bridge, was synthesized. The particular structure and topology of such a diradical allow a non-negligible spin density on the ferrocene moiety making feasible the magnetic coupling between the two organic radical units. In addition, the location of both radical units far away from each other avoids any possibility of having intramolecular hydrogen bond interactions, and consequently, a significant direct through-space magnetic interaction: O. Elsner, D. Ruiz-Molina, J. Vidal-Gancedo, C. Rovira, J. Veciana, Chem. Commun. (1999) 579.
    • (1999) Chem. Commun. , pp. 579
    • Elsner, O.1    Ruiz-Molina, D.2    Vidal-Gancedo, J.3    Rovira, C.4    Veciana, J.5
  • 11
    • 0031059866 scopus 로고    scopus 로고
    • C.W. Jr. Carter, Sweet R.M. New York: Academic Press
    • Otwinowski Z., Minor W. Carter C.W. Jr, Sweet R.M. Methods in Enzymology. 276:1996;307-326 Academic Press, New York.
    • (1996) Methods in Enzymology , vol.276 , pp. 307-326
    • Otwinowski, Z.1    Minor, W.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.