Kinetic modeling of the methanol to olefins process. 1. Model formulation

Industrial and Engineering Chemistry Research

Volumn 40, Issue 20, 2001, Pages 4172-4186

  Park, Tae Yun ^a,b   Froment, Gilbert F ^a,c  

^a GHENT UNIVERSITY   (Belgium)

^b NZ Legacy LLC   (United States)

^c Texas AandM University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ISOMERS; KINETIC ENERGY; METHANOL; OLEFINS; THERMODYNAMICS;

PLAUSIBLE MECHANISMS;

INDUSTRIAL RESEARCH;

ALKENE; METHANOL;

METHANOL; OLEFIN COPOLYMER; REACTION; THERMODYNAMICS;

ALGORITHM; ARTICLE; CALCULATION; CATALYST; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; ISOMER; MODEL; QUANTUM CHEMISTRY; REACTION ANALYSIS;

EID: 0035802175     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie0008530     Document Type: Article

References (16)

1. Eng, C. N.; Arnold, E. C.; Vora, B. V.; Fuglerud, T.; Kvisle, S.; Nilsen, H. Integration of the UOP/HYDRO MTO Process into Ethylene Plants. AIChE Spring National Meeting, 1998; Session 16.
2. Chang, C. D. Hydrocarbons from Methanol; Marcel Dekker: New York, 1983.
3. Froment, G. F.; Dehertog, W. J. H.; Marchi, A. J. Zeolite Catalysis in the Conversion of Methanol into Olefins. In Catalysis; Graham, T., Ed.; Royal Society of Chemistry: London, 1992; Vol. 9, p 1.
4. Marchi, A. J.; Froment, G. F. Catalytic Conversion of Methanol to Light Alkenes on SAPO Molecular Sieves. Appl. Catal. 1991, 71, 139.
5. Dehertog, W. J. H.; Froment, G. F. Production of Light Alkenes from Methanol on ZSM-5 Catalysts. Appl. Catal. 1991, 71, 153.
6. Inui, T.; Takeuchi, G.; Takegami, Y. A Composite Zeolite Catalyst For Olefin Synthesis Prepared by a Novel Metal Loading Method. Appl. Catal. 1982, 4, 211.
7. Hutchings, G. J.; Hunter, R. Hydrocarbon Formation from Methanol and Dimethyl ether: A Review of the Experimental Observation Concerning the Mechanism of Formation of the Primary Products. Catal. Today 1990, 6, 279.
8. Quann, R. J.; Green, L. A.; Tabak, S. A.; Krambeck, F. J. Chemistry of Olefin Oligomerization over ZSM-5 Catalyst. Ind. Eng. Chem. Res. 1988, 27, 565.
9. Poutsma, M. L. Mechanistic Considerations of Hydrocarbon Transformations Catalyzed by Zeolites. In Zeolite Chemistry and Catalysis; Rabo, J. A., Ed.; ACS Monograph Series 171; American Chemical Society: Washington, DC, 1976; p 437.
10. Martens, J. A.; Jacobs, P. A. Conceptual Background for the Conversion of Hydrocarbons on Heterogeneous Acid Catalysts. In Theoretical Aspects of Heterogeneous Catalysis; Moffat, J. B., Ed.; Van Nostrand Reinhold: New York, 1990; p 52.
11. Pines, H. Chemistry of Catalytic Hydrocarbon Conversions; Academic Press: New York, 1981.
12. Gates, B. C.; Katzer, J. R.; Schuit, G. C. Chemistry of Catalytic Processes; McGraw-Hill: New York, 1979.
13. Chen, N. Y.; Reagan, W. J. Evidence of Autocatalysis in Methanol to Hydrocarbon Reactions over Zeolite catalysts. J. Catal. 1979, 59, 123.
14. Chang, C. D. A Kinetic Model for Methanol Conversion to Hydrocarbons. Chem. Eng. Sci. 1980, 35, 619.
15. Mihail, R.; Straja, S.; Maria, G.; Musca, G.; Pop, G. Kinetic Model for Methanol to Olefins. Ind. Eng. Chem. Process Des. Dev. 1983, 22, 532.
16. Benito, P. L.; Gayubo, A. G.; Aguayo, A. T.; Castilla, M.; Bilbao, J. Concentration-Dependent Kinetic Model for Catalyst Deactivation in the MTG Process. Ind. Eng. Chem. Res. 1996, 35, 81.