A novel process for the catalytic polymerization of olefins in supercritical carbon dioxide

Chemical Engineering Science

Volumn 56, Issue 13, 2001, Pages 4197-4204

  Kemmere, Maartje ^a   De Vries, Tjerk ^a   Vorstman, Marius ^a   Keurentjes, Jos ^a  

^a EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

Brookhart catalyst; Cloud point measurements; Olefin polymerization; SAFT; Supercritical carbon dioxide

Indexed keywords

CARBON DIOXIDE; CATALYSTS; MOLECULAR WEIGHT; POLYMERIZATION; PURIFICATION; SOLUBILITY; SYNTHESIS (CHEMICAL); TERNARY SYSTEMS;

CATALYTIC POLYMERIZATIONS;

OLEFINS;

CATALYST; POLYMERIZATION; POLYOLEFIN; SUPERCRITICAL FLUID;

EID: 0035800558     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2509(01)00068-9     Document Type: Article

References (24)

1. A method for homo- or copolymerizing ethene
2. Polymerizable compositions comprising alpha-olefin hydrocarbon monomers and methods of use therefore
3. Palladium-catalyzed carbon-carbon formation in supercritical carbon dioxide
4. Polymer synthesis and processing using supercritical carbon dioxide
5. Fluid-phase equilibria in the system polythylene and ethylene, systems of linear polyethylene and ethylene at high pressure
6. Polymerisation of olefins catalysed by a palladium complex in supercritical carbon dioxide
7. The phase behavior of poly(ethylene-co-propylene) in ethylene and carbon dioxide: Experimental results and modeling with the SAFT EOS
8. Olefin metathesis in compressed carbon-dioxide
9. Opportunities for process intensification using reverse micelles in liquid and supercritical carbon dioxide
10. 2-solubility
11. Rhodium-catalyzed phenylacetylene polymerization in compressed carbon-dioxide
12. Modeling carbon dioxide sorption in poly(methyl methacrylate) combining the Sanchez-Lacombe and Lee-Kesler equations of state
13. Homogeneous catalysis in supercritical fluids
14. New Pd(II)-and Ni(II)-based catalysts for polymerization of ethylene and α-olefins
15. Perfluoralkyl-substituted arylphosphanes as ligands for homogeneous catalysis in supercritical carbon-dioxide
16. Polymerizations in supercritical carbon dioxide
17. Stabilized polymer microparticles by precipitation with a compressed antisolvent 2. poly(propylene oxide)- and poly (butylene oxide) based copolymers
18. High conversion emulsion polymerization
19. Mechanistic studies of palladium-catalyzed copolymerization of ethylene and α-olefins with methyl acrylate
20. Ring-opening metathesis polymerizations in carbon-dioxide
21. Copolymerization of 1,2-epoxycyclohexane and carbon-dioxide using carbon-dioxide as both reactant and solvent
22. Solubility of naphthalene in supercritical methane