Apparent solubility limit of nuclear glass

Materials Research Society Symposium - Proceedings

Volumn 663, Issue , 2001, Pages 217-225

  Vernaz, Étienne ^a   Gin, Stéphane ^a  

^a DIF   (France)

Author keywords

[No Author keywords available]

Indexed keywords

RADIOACTIVE WASTES; REACTION KINETICS; SILICON; SOLUBILITY; THERMAL EFFECTS;

NUCLEAR GLASS;

GLASS;

EID: 0035783107     PISSN: 02729172     EISSN: None     Source Type: Conference Proceeding    
DOI: None     Document Type: Conference Paper

References (14)

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2. S. Gin and É. Vernaz, Aqueous Alteration Mechanisms and Kinetics of French R7T7 Reference Glass in the Presence of Phosphate Ions, Ninth International Symposium on Water-Rock Interaction, Taupo, New Zealand, March 30-April 3, 1998.
3. B. Grambow (1985), A General Rate Equation for Nuclear Waste Glass Corrosion, in Scientific Basis for Nuclear Waste Management., Mat. Res. Soc. Symp. Proc., 44, 15-27.
4. É. Vernaz, S. Gin and I. Ribet (2000), Present understanding of glass alteration kinetics and their impact on Long-term behavior modeling, in International Workshop on Glass in its Disposal Environment, Bruges, April 2000 (to be published in J. Nucl. Mat.).
5. C. Jégou (1998), Mise en évidence expérimentale des mécanismes limitant la cinétique d'Altération du verre R7T7 en milieu aqueux: Critique et proposition d'Évolution du formalisme cinétique. Ph.D. thesis, Université de Montpellier II, France.
6. S. Gin (2000), Protective Effect of the Alteration Gel: A Key Mechanism in the Long-Term Behavior of Nuclear Waste Glass (this MRS Conf.).
7. S. Gin, C. Jégou and É. Vernaz, Nuclear Glass Alteration Kinetics: an Experimental Approach to Discriminate between the Affinity Effect and Protective Gel Effect, XVIII International Congress on Glass, San Francisco, July 5-10, 1998.
8. J. Schwartzentruber, W. Furst and H. Renon (1987), Dissolution of quartz into dilute alkaline solutions at 90°C: A kinetic study, Geochem. Cosmochim. Acta, 51, 1867-1874.
9. S. Gin, I. Ribet and M. Couillaud (2000), Role and Properties of the Gel Formed during Nuclear Glass Alteration: Importance of Gel Formation Conditions, in International Workshop on Glass in its Disposal Environment, Bruges, April 2000 (to be published in J. Nucl. Mat.).
10. C. Jégou, S. Gin and F. Larché (2000), Alteration Kinetics of a Simplified Nuclear Glass in an Aqueous Medium: Effects of Solution Chemistry and of Protective Gel Properties on Diminishing the Alteration Rate (accepted for publication in J. Nucl. Mat.).
11. Y. Linard (2000), Détermination des enthalpies libres de formation des verres borosilicatés, Ph.D. thesis, Institut de Physique du Globe, Université de Paris VII.
12. Adams and Gibbs (1965), On the temperature dependence of cooperative relaxation properties in glass-forming liquids, J. Chem. Phys. 43, 139.
13. L.A. Chick and L.R. Pederson (1984), The Relationship between Reaction Layer Thickness and Leach Rate for Nuclear Waste Glasses, in Scientific Basis for Nuclear Waste Management, Mat. Res. Soc. Symp. Proc., vol. 26, pp 635-642.
14. P. Jollivet, T. Montanelli and É. Vernaz, Modeling the Lifetime of High Level Containment Glass Package Under Various Disposal Conditions, Global '95 International Conference on Evaluation of Emerging Nuclear Fuel Cycle Systems, Versailles September 11-14, Proc. vol. 1, p 766.