Biomimetic intradiol-cleavage of catechols with incorporation of both atoms of O2: The role of the vacant coordination site on the iron center

Chemistry Letters

Volumn , Issue 10, 2001, Pages 1062-1063

  Ogo, Seiji ^a   Yamahara, Ryo ^b   Funabiki, Takuzo ^c   Masuda, Hideki ^b   Watanabe, Yoshihito ^a,d  

^a INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

^b NAGOYA INSTITUTE OF TECHNOLOGY   (Japan)

^c KYOTO UNIVERSITY   (Japan)

^d OKAZAKI INSTITUTE FOR INTEGRATIVE BIOSCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0035655717     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2001.1062     Document Type: Article

References (17)

1. T. Funabiki, in "Oxygenases and Model Systems, Catalysis by Metal Complexes" ed. by T. Funabiki, Kluwer, Dordrecht (1997), Chap. 2, p 19.
2. O. Hayaishi, M. Katagiri, and S. Rotheberg, J. Am. Chem. Soc., 77, 5450 (1955).
3. a) R. Yamahara, S. Ogo, Y. Watanabe, T. Funabiki, K. Jitsukawa, H. Masuda, and H. Einaga, Inorg. Chim. Acta, 300-302, 587 (2000).
4. b) D.-H. Jo and L. Que, Jr., Angew. Chem. Int. Ed., 39, 4284 (2000).
5. c) G. Lin, G. Reid, and T. D. H. Bugg, Chem. Commun., 2000, 1119.
6. d) T. Ogihara, S. Hikichi, M. Akita, and Y. Moro-oka, Inorg. Chem., 37, 2614 (1998).
7. e) W. O. Koch and H.-J. Krüger, Angew. Chem., Int. Ed. Engl., 34, 2671 (1995).
8. f) A. Dei, D. Gatteschi, and L. Pardi, Inorg. Chem., 32, 1389 (1993).
9. g) H. G. Jang, D. D. Cox, and L. Que, Jr., J. Am. Chem. Soc., 113, 9200 (1991).
10. h) T. Funabiki, A. Mizoguchi, T. Sugimoto, S. Tada, M. Tsuji, H. Sakamoto, and S. Yoshida, J. Am. Chem. Soc., 108, 2921 (1986).
11. a) M. W. Vetting, D. A. D'Argenio, L. N. Ornston, and D. H. Ohlendorf, Biochemistry, 39, 7943 (2000).
12. b) D. H. Ohlendorf, A. M. Orville, and J. D. Lipscomb, J. Mol. Biol., 244, 586 (1994).
13. c) D. H. Ohlendorf, J. D. Lipscomb, and P. C. Weber, Nature, 336, 403 (1988).
14. A. M. Orville, J. D. Lipscomb, and D. H. Ohlendorf, Biochemistry, 36, 10052 (1997).
15. w = 0.107, 10573 reflections used, 814 parameters. Crystallographic data for 1 have been deposited with the Cambridge Crystallographic Data Center as supplementary publication no. CCDC-153553.
16. The details of the crystal structure of 6 will be reported elsewhere in a full paper.
17. 2 (1 atm) in DMF at 25°C is 4.86 mM. Japan Chemical Society, Kagaku-Binran Basic Part II, 2nd edition, Maruzen, Tokyo, 775 (1975).