Isolable yet highly reactive cationic organoruthenium(II) amidinates, [Ru(η6-C6R6)(η-amidinate)] +X-, showing signs of coordinative unsaturation: Isoelectronic complexes of Ru(η5-C5Me5)(η-amidinate)

Chemistry Letters

Volumn , Issue 10, 2001, Pages 954-955

  Hayashida, Taizo ^a   Yamaguchi, Yoshitaka ^a,c   Kirchner, Karl ^b   Nagashima, Hideo ^a  

^a KYUSHU UNIVERSITY   (Japan)

^b VIENNA UNIVERSITY OF TECHNOLOGY   (Austria)

^c YOKOHAMA NATIONAL UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0035650391     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2001.954     Document Type: Article

References (21)

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15. 3).
16. 2 = 0.1584 (all data).
17. 7b the counter anion of which coordinates to the metal center.
18. a) M. Ogasawara, D. Huang, W. E. Streib, J. C. Huffman, N. Gallego-Planas, F. Maseras, O. Eisenstein, and K. G. Caulton, J. Am. Chem. Soc., 119, 8642 (1997).
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20. All calculations were performed using the Gaussian 98 software package on the Silicon Graphics Power Challenge of the Vienna University of Technology. The geometry and energy of the model complex and the transition state were optimized at the B3LYP level with the Stuttgart/Dresden ECP (SDD) basis set to describe the electrons of the ruthenium atom. For all other atoms the 6-31G** basis set was employed.
21. -1.