A stepwise growth of polyoxovanadate by reductive coupling reaction with organometallic palladium complex: Formation of [{(η3-C4H7)Pd}2V4O12]2-, [V10O26]4- and [V15O36(Cl)]4-

Chemistry Letters

Volumn , Issue 2, 2001, Pages 170-171

  Hayashi, Yoshihito ^a   Miyakoshi, Noboru ^a   Shinguchi, Takayuki ^a   Uehara, Akira ^a  

^a KANAZAWA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0035648187     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2001.170     Document Type: Article

References (22)

1. a) M. T. Pope and A. Müller, Angew. Chem., Int. Ed. Engl., 30, 34 (1991).
2. b) A. Müller, H. Reuter, and S. Dillinger, Angew. Chem., Int. Ed. Engl., 34, 2328 (1995).
3. a) A. Müller, J. Mol. Struct., 325, 13 (1994).
4. b) A. Müller, R. Sessoli, E. Krickemeyer, H. Bögge, J. Meyer, D. Gatteschi, L. Pardi, J. Westphal, K. Hovemeier, R. Rohlfing, J. Döring, F. Hellweg, C. Beugholt, and M. Schmidtmann, Inorg. Chem., 36 5239 (1997).
5. 3): δ(ppm) = -504 (s).
6. -3.
7. a) V. W. Day, W. G. Klemperer, and A. Yagasaki, Chem. Lett., 1990, 1267.
8. b) H. Akashi, K. lsobe, Y. Ozawa, and A. Yagasaki. J. Cluster Sci., 2, 291 (1991).
9. c) M. Abe, K. Isobe, K. Kida, A. Nagasawa, and A. Yagasaki, J. Cluster Sci., 5, 565 (1994).
10. d) M. Abe, H. Akashi, K. Isobe, A. Nakanishi, and A. Yagasaki, J. Cluster Sci., 7, 103 (1996).
11. e) M. Abe, K. Isobe, K. Kida, and A. Yagasaki, Inorg. Chem., 35, 5114 (1996).
12. -1): 997 (m), 970 (s), 957 (s), 926 (s), 891 (vs), 843 (s), 659 (s).
13. + cations exhibited considerable disorder, and the parts of bond lengths were constrained.
14. a) A. Bino, S. Cohen, and C. Heitner-Wirguin, Inorg. Chem., 21, 429 ( 1982).
15. b) S. M. Baxter and P. T. Wolczanski, Inorg. Chem., 28, 3263 (1989).
16. c) C. Heitner-Wirguin and J. Selbin, J. Inorg. Nucl. Chem., 30, 3181 (1968).
17. -1): 997 (s, br). 980 (s, sh), 887 (m), 874 (m), 798 (m).
18. -3-'. The anion is on a four-fold rotary inversion axis through O(11), Cl, V(5) and O(5) with an inversion point at the position of Cl. Thus, the anion occupying each site in two orientations resulting in the disorder between [V(4)=O(4)-O(11)-V(4′)=O(4′)] group and V(5)=O(5) group(1:1).
19. a) A. Müller, E. Krickemeyer, M. Penk, H-J. Walberg, and H. Bögge. Angew. Chem., Int. Ed. Engl., 26, 1045 (1987).
20. b) A. Müller, M. Penk, R. Rohlfing, E. Krickemeyer, and J. Döring, Angew. Chem., Int. Ed. Engl., 29, 926 (1990).
21. c) A. Müller, R. Rohlfing, E. Krickemeyer, and H. Bögge, Angew. Chem., Int. Ed. Engl. 32, 909 ( 1993).
22. d) T. Yamase and K. Ohtaka, J. Chem. Soc., Dalton Trans., 1994, 2599.