Structure and magnetic property of a macrocyclic tetranuclear copper(II) complex with phenoxo-and hydroxo-bridges and large and small Cu-O-Cu angles

Chemistry Letters

Volumn , Issue 4, 2001, Pages 316-317

  Handa, Makoto ^a   Takemoto, Toshikazu ^a   Thompson, Laurence K ^b   Mikuriya, Masahiro ^c   Nagao, Nobuyuki ^c   Ikemi, Shinichiro ^c   Lim, Jong Wan ^c   Sugimori, Tamotsu ^a   Hiromitsu, Ichiro ^a   Kasuga, Kuninobu ^a  

^a SHIMANE UNIVERSITY   (Japan)

^b MEMORIAL UNIVERSITY OF NEWFOUNDLAND   (Canada)

^c KWANSEI GAKUIN UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0035625788     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2001.316     Document Type: Article

References (17)

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8. w = 0.068 for 5850 (I>3σ(I)) observed reflections from 7549 unique data. For the determination of structure, intensity data were collected on a Rigaku RAXIS-rapid imaging plate area detector with graphite monochromated Mo Kα radiation. The intensity data were corrected for Lorentz-polarization effects. The structure was solved by direct method and refined by the full-matrix least-squares method using teXsan program package.
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10. 4 (6): C, 34.91; H, 3.91; N, 6.78%.
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12. -1 with g = 2.1). Similar treatment can be seen for tetranuclear copper(II) complexes in ref 14, in which monomeric and dimeric impurities are taken into consideration.
13. 1)).
14. 1/2.
15. S. S. Tandon, S. K. Mandal, L. K. Thompson, and R. C. Hynes, J. Chem. Soc., Chem. Commn., 1991, 1572; S. S. Tandon, S. K. Mandal, L. K. Thompson, and R. C. Hynes, Inorg. Chem., 31, 2215 (1992).
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17. -1 (R = 0.044).